The DOI matches its Crossref record.
C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation
Abstract
Rhodium(III)-catalyzed direct functionalization of C-H bonds under oxidative conditions leading to C-C, C-N, and C-O bond formation is reviewed. Various arene substrates bearing nitrogen and oxygen directing groups are covered in their coupling with unsaturated partners such as alkenes and alkynes. The facile construction of C-E (E = C, N, S, or O) bonds makes Rh(III) catalysis an attractive step-economic approach to value-added molecules from readily available starting materials. Comparisons and contrasts between rhodium(III) and palladium(II)-catalyzed oxidative coupling are made. The remarkable diversity of structures accessible is demonstrated with various recent examples, with a proposed mechanism for each transformation being briefly summarized (critical review, 138 references).
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Cited by
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Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups
Chen, Z., Wang, B., Zhang, J., Yu, W., Liu, Z., & Zhang, Y. (2015) · Organic Chemistry Frontiers · doi:10.1039/c5qo00004a · Cited by 1,533
Transition-Metal-Catalyzed, Coordination-Assisted Functionalization of Nonactivated C(sp3)–H Bonds
Liu, B., Romine, A. M., Rubel, C. Z., Engle, K. M., & Shi, B.-F. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00519 · Cited by 538
Egorova, K. S., & Ananikov, V. P. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201603777 · Cited by 490
Ikemoto, H., Yoshino, T., Sakata, K., Matsunaga, S., & Kanai, M. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5008432 · Cited by 466
Parasram, M., & Gevorgyan, V. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00226b · Cited by 462
General Enantioselective C−H Activation with Efficiently Tunable Cyclopentadienyl Ligands
Jia, Z., Merten, C., Gontla, R., Daniliuc, C. G., Antonchick, A. P., & Waldmann, H. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201611981 · Cited by 336
Yu, S., Liu, S., Lan, Y., Wan, B., & Li, X. (2015) · Journal of the American Chemical Society · doi:10.1021/ja511796h · Cited by 331
Self-citationFormation of CX Bonds in CO2 Chemical Fixation Catalyzed by Metal−Organic Frameworks
Hou, S., Dong, J., & Zhao, B. (2020) · Advanced Materials · doi:10.1002/adma.201806163 · Cited by 142
Metadata
- Authors
- Song, G., Wang, F., & Li, X.
- Venue
- Chemical Society Reviews
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 41
- Issue
- 9
- Pages
- 3651
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W2104742517
- Cited by
- 2,302
- References
- 0
- FWCI
- 9.24
- Type
- journal article
- Language
- en
- Open access
- closed
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