The DOI matches its Crossref record; 21 of the 21 references it cites were found in a registry or an index.
General Enantioselective C−H Activation with Efficiently Tunable Cyclopentadienyl Ligands
Abstract
Cyclopentadienyl (Cp) ligands enable efficient steering of various transition‐metal‐catalyzed transformations, in particular enantioselective C−H activation. Currently only few chiral Cp ligands are available. Therefore, a conceptually general approach to chiral Cp ligand discovery would be invaluable as it would enable the discovery of applicable Cp ligands and to efficiently and rapidly vary and tune their structures. Herein, we describe the three‐step gram‐scale synthesis of a structurally diverse and widely applicable chiral Cp ligand collection (JasCp ligands) with highly variable and adjustable structures. Their modular nature and their amenability to rapid structure variation enabled the efficient discovery of ligands for three enantioselective Rh III‐catalyzed C−H activation reactions, including one unprecedented transformation. This novel approach should enable the discovery of efficient chiral Cp ligands for various further enantioselective transformations.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
New Chiral Phosphorus Ligands for Enantioselective Hydrogenation
Tang, W., & Zhang, X. (2003) · Chemical Reviews · doi:10.1021/cr020049i · Cited by 2,570
C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation
Song, G., Wang, F., & Li, X. (2012) · Chemical Society Reviews · doi:10.1039/c2cs15281a · Cited by 2,302
Parmar, D., Sugiono, E., Raja, S., & Rueping, M. (2014) · Chemical Reviews · doi:10.1021/cr5001496 · Cited by 2,118
Atroposelective Total Synthesis of Axially Chiral Biaryl Natural Products
Bringmann, G., Gulder, T., Gulder, T. A. M., & Breuning, M. (2010) · Chemical Reviews · doi:10.1021/cr100155e · Cited by 1,458
Recent advances and new concepts for the synthesis of axially stereoenriched biaryls
Wencel-Delord, J., Panossian, A., Leroux, F. R., & Colobert, F. (2015) · Chemical Society Reviews · doi:10.1039/c5cs00012b · Cited by 994
Guimond, N., Gorelsky, S. I., & Fagnou, K. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201143v · Cited by 941
Assessing Atropisomer Axial Chirality in Drug Discovery and Development
LaPlante, S. R., Fader, L. D., Fandrick, K. R., Fandrick, D. R., Hucke, O., Kemper, R., Miller, S. P. F., & Edwards, P. J. (2011) · Journal of Medicinal Chemistry · doi:10.1021/jm200584g · Cited by 861
Biotinylated Rh(III) Complexes in Engineered Streptavidin for Accelerated Asymmetric C–H Activation
Hyster, T. K., Knörr, L., Ward, T. R., & Rovis, T. (2012) · Science · doi:10.1126/science.1226132 · Cited by 814
The Challenge of Atropisomerism in Drug Discovery
Clayden, J., Moran, W. J., Edwards, P. J., & LaPlante, S. R. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200901719 · Cited by 783
Xie, J.-H., & Zhou, Q.-L. (2008) · Accounts of Chemical Research · doi:10.1021/ar700137z · Cited by 774
Metadata
- Authors
- Jia, Z., Merten, C., Gontla, R., Daniliuc, C. G., Antonchick, A. P., & Waldmann, H.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2017-01-26
- Volume
- 56
- Issue
- 9
- Pages
- 2429-2434
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2582614442
- Cited by
- 336
- References
- 21
- FWCI
- 17.69
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: General Enantioselective C−H Activation with Efficiently Tunable Cyclopentadienyl Ligands. https://app.cochat.ai/papers/10.1002/anie.201611981
- The paper
- Jia, Z., Merten, C., Gontla, R., Daniliuc, C. G., Antonchick, A. P., & Waldmann, H. (2017). General Enantioselective C−H Activation with Efficiently Tunable Cyclopentadienyl Ligands. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201611981
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
