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Lanthanide complexes as chiral probes exploiting circularly polarized luminescence
Open accessAbstract
Optical probes that provide information about local chirality have been developed based on changes to the circular polarisation of emitted light. Highly emissive complexes of lanthanide ions are ideally suited for CPL spectroscopy and the design criteria for developing such probes are defined, based on a rigorous stereochemical analysis. The perturbation of a dynamically racemic complex may occur either by a change in complex constitution or by non-covalent association. With complexes of enantiopure ligands, perturbation may involve either dynamic helicity inversion or a reversible change in the lanthanide coordination environment.
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Citations
Cited by
Supramolecular Chirality in Self-Assembled Systems
Liu, M., Zhang, L., & Wang, T. (2015) · Chemical Reviews · doi:10.1021/cr500671p · Cited by 2,250
Circularly Polarized Luminescence in Nanoassemblies: Generation, Amplification, and Application
Sang, Y., Han, J., Zhao, T., Duan, P., & Liu, M. (2020) · Advanced Materials · doi:10.1002/adma.201900110 · Cited by 1,162
Lanthanide Circularly Polarized Luminescence: Bases and Applications
Zinna, F., & Di Bari, L. (2015) · Chirality · doi:10.1002/chir.22382 · Cited by 608
Song, F., Xu, Z., Zhang, Q., Zhao, Z., Zhang, H., Zhao, W., Qiu, Z., Qi, C., Zhang, H., Sung, H. H. Y., et al. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201800051 · Cited by 432
Symmetry Breaking in Self-Assembled Nanoassemblies
Sang, Y., & Liu, M. (2019) · Symmetry · doi:10.3390/sym11080950 · Cited by 35
“As one kind of the excited-state optical activity, circularly polarized light (CPL) has triggered intense research interests due to their potential applications in optical sensors [130,131], 3D displays [132,133], bioencoding [130,134,135], encrypted transmission, and storage of information [136], chiral catalysts [13…”
Background
Metadata
- Authors
- Carr, R., Evans, N. H., & Parker, D.
- Venue
- Chemical Society Reviews
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 41
- Issue
- 23
- Pages
- 7673
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W2169203808
- Cited by
- 784
- References
- 0
- FWCI
- 0.99
- Type
- journal article
- Language
- en
- Open access
- green
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