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Cited by 432

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Highly Efficient Circularly Polarized Electroluminescence from Aggregation‐Induced Emission Luminogens with Amplified Chirality and Delayed Fluorescence

Song, Fengyan, Xu, Zeng, Zhang, Qiushuo, Zhao, Zheng, Zhang, Haoke, Zhao, Weijun, Qiu, Zijie, Qi, Chunxuan, Zhang, Han, Sung, Herman H. Y., Williams, Ian D., Lam, Jacky W. Y., Zhao, Zujin, Qin, Anjun, Ma, Dongge, Tang, Ben Zhong·2018·Advanced Functional Materials

Abstract

Development of highly efficient circularly polarized organic light‐emitting diodes (CPOLEDs) has gained increasing interest as they show improved luminous efficiency and high contract 3D images in OLED displays. In this work, a series of binaphthalene‐containing luminogenic enantiomers with aggregation‐induced emission (AIE) and delayed fluorescence properties is designed and synthesized. These molecules can emit from green to red light depending on the solvent polarity due to the twisted intramolecular charge transfer effect. However, their solid powders show bright light emissions, demonstrating a phenomenon of AIE. All the molecules exhibit Cotton effects and circularly polarized luminescence in toluene solution and films. Multilayer CPOLEDs using the doped and neat films of the molecules as emitting layers are fabricated, which exhibit high external quantum efficiency of up to 9.3% and 3.5% and electroluminescence dissymmetry factor (gEL) of up to +0.026/−0.021 and +0.06/−0.06, respectively. Compared with doped CPOLEDs, the nondoped ones show higher gEL and much smaller current efficiency roll‐off due to the stronger AIE effect. By altering the donor unit, the electroluminescence maximum of the doped film can vary from 493 to 571 nm. As far as it is known, this is the first example of efficient CPOLEDs based on small chiral organic molecules.

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Metadata

Authors
Song, F., Xu, Z., Zhang, Q., Zhao, Z., Zhang, H., Zhao, W., Qiu, Z., Qi, C., Zhang, H., Sung, H. H. Y., Williams, I. D., Lam, J. W. Y., Zhao, Z., Qin, A., Ma, D., & Tang, B. Z.
Venue
Advanced Functional Materials
Publisher
Wiley
Published
2018-02-28
Volume
28
Issue
17
ISSN
  • 1616-301X (ISSN-L)
  • 1616-3028
OpenAlex
W2789351668
Cited by
432
References
47
FWCI
18.35
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Highly Efficient Circularly Polarized Electroluminescence from Aggregation‐Induced Emission Luminogens with Amplified Chirality and Delayed Fluorescence. https://app.cochat.ai/papers/10.1002/adfm.201800051
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Song, F., Xu, Z., Zhang, Q., Zhao, Z., Zhang, H., Zhao, W., Qiu, Z., Qi, C., Zhang, H., Sung, H. H. Y., Williams, I. D., Lam, J. W. Y., Zhao, Z., Qin, A., Ma, D., & Tang, B. Z. (2018). Highly Efficient Circularly Polarized Electroluminescence from Aggregation‐Induced Emission Luminogens with Amplified Chirality and Delayed Fluorescence. Advanced Functional Materials. https://doi.org/10.1002/adfm.201800051

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