The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Tuning the catalytic performance of metal–organic frameworks in fine chemistry by active site engineering
Abstract
The effect of a post-synthetic acid treatment on the catalytic performance of MOFs is evaluated for MIL-100(Fe), an iron-benzenetricarboxylate. The acid-treated frameworks are structurally robust as no differences have been found in XRD patterns after treatment. Porosity of the acid-treated MOFs gradually decreases, most probably as a consequence of anions remaining in the charged frameworks. Monitoring the modification of the MOFs by reactions of which the outcome depends on the acid properties of the catalyst suggests the presence of two types of active sites, with weak Brönsted acid sites in close vicinity to the Lewis acid open metal sites. This is supported by CO-chemisorption experiments which indicate a large increase of both Lewis and Brönsted acidity. In Diels–Alder reactions of oxygenated dienophiles with 1,3-cyclohexadiene, a strong increase of the activity is found for the acid-treated MOFs. This is explained by the enhanced activation of the dienophiles on the modified active sites.
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Citations
Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Cited by
The Chemistry and Applications of Metal-Organic Frameworks
Furukawa, H., Cordova, K. E., O’Keeffe, M., & Yaghi, O. M. (2013) · Science · doi:10.1126/science.1230444 · Cited by 16,945
From fundamentals to applications: a toolbox for robust and multifunctional MOF materials
Kirchon, A., Feng, L., Drake, H. F., Joseph, E. A., & Zhou, H.-C. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00688a · Cited by 1,448
Defect‐Engineered Metal–Organic Frameworks
Fang, Z., Bueken, B., De Vos, D. E., & Fischer, R. A. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201411540 · Cited by 1,252
Self-citationVermoortele, F., Bueken, B., Le Bars, G., Van de Voorde, B., Vandichel, M., Houthoofd, K., Vimont, A., Daturi, M., Waroquier, M., Van Speybroeck, V., et al. (2013) · Journal of the American Chemical Society · doi:10.1021/ja405078u · Cited by 1,110
Self-citationMetal–organic and covalent organic frameworks as single-site catalysts
Rogge, S. M. J., Bavykina, A., Hajek, J., Garcia, H., Olivos-Suarez, A. I., Sepúlveda-Escribano, A., Vimont, A., Clet, G., Bazin, P., Kapteijn, F., et al. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00033b · Cited by 1,077
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Metadata
- Authors
- Vermoortele, F., Ameloot, R., Alaerts, L., Matthessen, R., Carlier, B., Fernandez, E. V. R., Gascon, J., Kapteijn, F., & De Vos, D. E.
- Venue
- Journal of Materials Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 22
- Issue
- 20
- Pages
- 10313
- ISSN
- 0959-9428 (ISSN-L)
- 1364-5501
- OpenAlex
- W2111801994
- Cited by
- 205
- References
- 1
- FWCI
- 7.87
- Type
- journal article
- Language
- en
- Open access
- closed
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- Vermoortele, F., Ameloot, R., Alaerts, L., Matthessen, R., Carlier, B., Fernandez, E. V. R., Gascon, J., Kapteijn, F., & De Vos, D. E. (2012). Tuning the catalytic performance of metal–organic frameworks in fine chemistry by active site engineering. Journal of Materials Chemistry. https://doi.org/10.1039/c2jm16030g
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