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Furan substituted diketopyrrolopyrrole and thienylenevinylene based low band gap copolymer for high mobility organic thin film transistors
Abstract
A novel solution processable donor–acceptor (D–A) based low band gap polymer semiconductor poly{3,6-difuran-2-yl-2,5-di(2-octyldodecyl)-pyrrolo[3,4-c]pyrrole-1,4-dione-alt-thienylenevinylene} (PDPPF-TVT), was designed and synthesized by a Pd-catalyzed Stille coupling route. An electron deficient furan based diketopyrrolopyrrole (DPP) block and electron rich thienylenevinylene (TVT) donor moiety were attached alternately in the polymer backbone. The polymer exhibited good solubility, film forming ability and thermal stability. The polymer exhibits wide absorption bands from 400 nm to 950 nm (UV-vis-NIR region) with absorption maximum centered at 782 nm in thin film. The optical band gap (Eoptg) calculated from the polymer film absorption onset is around 1.37 eV. The π-energy band level (ionization potential) calculated by photoelectron spectroscopy in air (PESA) for PDPPF-TVT is around 5.22 eV. AFM and TEM analyses of the polymer reveal nodular terrace morphology with optimized crystallinity after 200 °C thermal annealing. This polymer exhibits p-channel charge transport characteristics when used as the active semiconductor in organic thin-film transistor (OTFT) devices. The highest hole mobility of 0.13 cm2 V−1 s−1 is achieved in bottom gate and top-contact OTFT devices with on/off ratios in the range of 106–107. This work reveals that the replacement of thiophene by furan in DPP copolymers exhibits such a high mobility, which makes DPP furan a promising block for making a wi…
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“DPP-based molecules usually show high charge carrier mobilities due to their rigid and planar aromatic structures that facilitate the intermolecular packing.”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [85]
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Cites
Conjugated poly(thiophenes): synthesis, functionalization, and applications
Roncali, J. (1992) · Chemical Reviews · doi:10.1021/cr00012a009 · Cited by 2,787
π-Conjugated Polymers for Organic Electronics and Photovoltaic Cell Applications
Facchetti, A. F. (2010) · Chemistry of Materials · doi:10.1021/cm102419z · Cited by 2,393
Synthetic Principles for Bandgap Control in Linear π-Conjugated Systems
Roncali, J. (1997) · Chemical Reviews · doi:10.1021/cr950257t · Cited by 2,187
Liquid-crystalline semiconducting polymers with high charge-carrier mobility
McCulloch, I. A., Heeney, M., Bailey, C., Genevičius, K., MacDonald, I. I., Shkunov, M. N., Sparrowe, D., Tierney, S., Wagner, R., Zhang, W., et al. (2006) · Nature Materials · doi:10.1038/nmat1612 · Cited by 2,149
Charge Carrier Transporting Molecular Materials and Their Applications in Devices
Shirota, Y., & Kageyama, H. (2007) · Chemical Reviews · doi:10.1021/cr050143+ · Cited by 1,776
Beaujuge, P. M., & Fréchet, J. M. J. (2011) · Journal of the American Chemical Society · doi:10.1021/ja2073643 · Cited by 1,447
Chen, J., & Cao, Y. (2009) · Accounts of Chemical Research · doi:10.1021/ar900061z · Cited by 1,405
Self-citationOrganic Semiconductors for Solution‐Processable Field‐Effect Transistors (OFETs)
Allard, S., Förster, M., Souharce, B., Thiem, H., & Scherf, U. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200701920 · Cited by 1,210
Bronstein, H. A., Chen, Z., Ashraf, R. S., Zhang, W., Du, J., Durrant, J. R., Tuladhar, P. S., Song, K., Watkins, S. E., Geerts, Y. H., et al. (2011) · Journal of the American Chemical Society · doi:10.1021/ja110619k · Cited by 902
Semiconductors for organic transistors
Facchetti, A. F. (2007) · Materials Today · doi:10.1016/s1369-7021(07)70017-2 · Cited by 894
Research works printed but not linked: 3
- Bijleveld, 2011, J. Mater. Chem., 21, 9424
- Sonar, 2012, J. Mater. Chem., 22, 4225
- Kline, 2006, Polym. Rev., 46, 27
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Metadata
- Authors
- Sonar, P., Zhuo, J.-M., Zhao, L.-H., Lim, K.-M., Chen, J., Rondinone, A. J., Singh, S. P., Chua, L.-L., Ho, P. K. H., & Dodabalapur, A.
- Affiliations
- Agency for Science, Technology and Research (SG)
- National University of Singapore (SG)
- Oak Ridge National Laboratory (US)
- Corresponding author
- Sonar, Prashant
- Chua, Lay-Lay
- ORCID
- Venue
- Journal of Materials Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 22
- Issue
- 33
- Pages
- 17284
- ISSN
- 0959-9428 (ISSN-L)
- 1364-5501
- OpenAlex
- W2135761533
- Cited by
- 57
- References
- 35
- Citations by year
- 2025: 1 · 2024: 2 · 2023: 1 · 2022: 5 · 2021: 1 · 2020: 4 · 2019: 3 · 2018: 3 · 2017: 4 · 2016: 5 · 2015: 10 · 2014: 10 · 2013: 5 · 2012: 3
- FWCI
- 5.73
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Materials Chemistry (publishedVersion)
- National University of Singapore (submittedVersion)
- Funders
- Institute of Materials Research and Engineering
- Oak Ridge National Laboratory
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Electronics and Photovoltaics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Light-Emitting Diodes Research
- Physical Sciences › Materials Science › Polymers and Plastics › Conducting polymers and applications
- Keywords
- diketopyrrolopyrrole, donor-acceptor polymers, low band gap polymers, organic thin-film transistors, hole mobility, UV-Vis-NIR absorption, ionization potential, annealing, crystallinity, organic electronics
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