The DOI matches its Crossref record; 35 of the 35 references it cites were found in a registry or an index.
Furan substituted diketopyrrolopyrrole and thienylenevinylene based low band gap copolymer for high mobility organic thin film transistors
Abstract
A novel solution processable donor–acceptor (D–A) based low band gap polymer semiconductor poly{3,6-difuran-2-yl-2,5-di(2-octyldodecyl)-pyrrolo[3,4-c]pyrrole-1,4-dione-alt-thienylenevinylene} (PDPPF-TVT), was designed and synthesized by a Pd-catalyzed Stille coupling route. An electron deficient furan based diketopyrrolopyrrole (DPP) block and electron rich thienylenevinylene (TVT) donor moiety were attached alternately in the polymer backbone. The polymer exhibited good solubility, film forming ability and thermal stability. The polymer exhibits wide absorption bands from 400 nm to 950 nm (UV-vis-NIR region) with absorption maximum centered at 782 nm in thin film. The optical band gap (Eoptg) calculated from the polymer film absorption onset is around 1.37 eV. The π-energy band level (ionization potential) calculated by photoelectron spectroscopy in air (PESA) for PDPPF-TVT is around 5.22 eV. AFM and TEM analyses of the polymer reveal nodular terrace morphology with optimized crystallinity after 200 °C thermal annealing. This polymer exhibits p-channel charge transport characteristics when used as the active semiconductor in organic thin-film transistor (OTFT) devices. The highest hole mobility of 0.13 cm2 V−1 s−1 is achieved in bottom gate and top-contact OTFT devices with on/off ratios in the range of 106–107. This work reveals that the replacement of thiophene by furan in DPP copolymers exhibits such a high mobility, which makes DPP furan a promising block for making a wi…
Overview
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
In the citing paper
“DPP-based molecules usually show high charge carrier mobilities due to their rigid and planar aromatic structures that facilitate the intermolecular packing.”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [85]
Citations
Cites
Conjugated poly(thiophenes): synthesis, functionalization, and applications
Roncali, J. (1992) · Chemical Reviews · doi:10.1021/cr00012a009 · Cited by 2,787
π-Conjugated Polymers for Organic Electronics and Photovoltaic Cell Applications
Facchetti, A. F. (2010) · Chemistry of Materials · doi:10.1021/cm102419z · Cited by 2,393
Synthetic Principles for Bandgap Control in Linear π-Conjugated Systems
Roncali, J. (1997) · Chemical Reviews · doi:10.1021/cr950257t · Cited by 2,187
Liquid-crystalline semiconducting polymers with high charge-carrier mobility
McCulloch, I. A., Heeney, M., Bailey, C., Genevičius, K., MacDonald, I. I., Shkunov, M. N., Sparrowe, D., Tierney, S., Wagner, R., Zhang, W., et al. (2006) · Nature Materials · doi:10.1038/nmat1612 · Cited by 2,149
Charge Carrier Transporting Molecular Materials and Their Applications in Devices
Shirota, Y., & Kageyama, H. (2007) · Chemical Reviews · doi:10.1021/cr050143+ · Cited by 1,776
Beaujuge, P. M., & Fréchet, J. M. J. (2011) · Journal of the American Chemical Society · doi:10.1021/ja2073643 · Cited by 1,447
Chen, J., & Cao, Y. (2009) · Accounts of Chemical Research · doi:10.1021/ar900061z · Cited by 1,405
Self-citationOrganic Semiconductors for Solution‐Processable Field‐Effect Transistors (OFETs)
Allard, S., Förster, M., Souharce, B., Thiem, H., & Scherf, U. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200701920 · Cited by 1,210
Bronstein, H. A., Chen, Z., Ashraf, R. S., Zhang, W., Du, J., Durrant, J. R., Tuladhar, P. S., Song, K., Watkins, S. E., Geerts, Y. H., et al. (2011) · Journal of the American Chemical Society · doi:10.1021/ja110619k · Cited by 902
Semiconductors for organic transistors
Facchetti, A. F. (2007) · Materials Today · doi:10.1016/s1369-7021(07)70017-2 · Cited by 894
Poly(diketopyrrolopyrrole−terthiophene) for Ambipolar Logic and Photovoltaics
Bijleveld, J. C., Zoombelt, A. P., Mathijssen, S. G. J., Wienk, M. M., Turbiez, M. G. R., de Leeuw, D. M., & Janssen, R. A. J. (2009) · Journal of the American Chemical Society · doi:10.1021/ja907506r · Cited by 757
Diketopyrrolopyrrole (DPP)-based materials for organic photovoltaics
Qu, S., & Tian, H. (2012) · Chemical Communications · doi:10.1039/c2cc17886a · Cited by 657
A High Mobility P‐Type DPP‐Thieno[3,2‐b]thiophene Copolymer for Organic Thin‐Film Transistors
Li, Y., Singh, S. P., & Sonar, P. M. (2010) · Advanced Materials · doi:10.1002/adma.201002313 · Cited by 547
Self-citationIncorporation of Furan into Low Band-Gap Polymers for Efficient Solar Cells
Woo, C. H., Beaujuge, P. M., Holcombe, T. W., Lee, O. P., & Fréchet, J. M. J. (2010) · Journal of the American Chemical Society · doi:10.1021/ja108115y · Cited by 463
High‐Mobility Ambipolar Near‐Infrared Light‐Emitting Polymer Field‐Effect Transistors
Bürgi, L., Turbiez, M. G. R., Pfeiffer, R., Bienewald, F., Kirner, H.-J., & Winnewisser, C. (2008) · Advanced Materials · doi:10.1002/adma.200702775 · Cited by 440
Sonar, P. M., Singh, S. P., Li, Y., Soh, M. S., & Dodabalapur, A. (2010) · Advanced Materials · doi:10.1002/adma.201002973 · Cited by 428
Self-citationHa, J. S., Kim, K. H., & Choi, D. H. (2011) · Journal of the American Chemical Society · doi:10.1021/ja203189h · Cited by 349
Organic and polymer transistors for electronics
Dodabalapur, A. (2006) · Materials Today · doi:10.1016/s1369-7021(06)71444-4 · Cited by 296
Self-citationThiophene Polymer Semiconductors for Organic Thin‐Film Transistors
Ong, B. S., Wu, Y., Li, Y., Liu, P., & Pan, H. (2008) · Chemistry - A European Journal · doi:10.1002/chem.200701717 · Cited by 293
Sonar, P. M., Singh, S. P., Li, Y., Ooi, Z., Ha, T., Wong, H., Soh, M. S., & Dodabalapur, A. (2011) · Energy & Environmental Science · doi:10.1039/c1ee01213d · Cited by 174
Self-citationShahid, M., McCarthy‐Ward, T., Labram, J. G., Rossbauer, S., Domingo, E. B., Watkins, S. E., Stingelin, N., Anthopoulos, T. D., & Heeney, M. (2011) · Chemical Science · doi:10.1039/c1sc00477h · Cited by 174
Bijleveld, J. C., Karsten, B. P., Mathijssen, S. G. J., Wienk, M. M., de Leeuw, D. M., & Janssen, R. A. J. (2010) · Journal of Materials Chemistry · doi:10.1039/c0jm03137b · Cited by 161
Nelson, T. L., Young, T., Liu, J., Mishra, S. P., Belot, J. A., Balliet, C. L., Javier, A. E., Kowalewski, T., & McCullough, R. D. (2010) · Advanced Materials · doi:10.1002/adma.201001599 · Cited by 156
Conjugated polymers containing diketopyrrolopyrrole units in the main chain
Tieke, B., Rabindranath, A. R., Zhang, K. A. I., & Zhu, Y. (2010) · Beilstein Journal of Organic Chemistry · doi:10.3762/bjoc.6.92 · Cited by 154
Li, Y., Sonar, P. M., Singh, S. P., Zeng, W., & Soh, M. S. (2011) · Journal of Materials Chemistry · doi:10.1039/c1jm11290b · Cited by 147
Self-citationLin, H.-W., Lee, W., & Chen, W. (2011) · Journal of Materials Chemistry · doi:10.1039/c1jm14640h · Cited by 145
Lim, B., Baeg, K., Jeong, H., Jo, J., Kim, H., Park, J., Noh, Y., Vak, D., Park, J., Park, J., et al. (2009) · Advanced Materials · doi:10.1002/adma.200803700 · Cited by 127
Emeraldicene as an Acceptor Moiety: Balanced‐Mobility, Ambipolar, Organic Thin‐Film Transistors
Mohebbi, A. R., Yuen, J. D., Fan, J., Munoz, C., Wang, M. F., Shirazi, R. S., Seifter, J., & Wudl, F. (2011) · Advanced Materials · doi:10.1002/adma.201102726 · Cited by 106
Zhuo, J., Zhao, L., Png, R., Wong, L., Chia, P., Tang, J., Sivaramakrishnan, S., Zhou, M., Ou, E. C. ‐., Chua, S. J., et al. (2009) · Advanced Materials · doi:10.1002/adma.200901120 · Cited by 96
Self-citationNew Poly(arylene vinylene)s Based on Diketopyrrolopyrrole for Ambipolar Transistors
Wu, P.-T., Kim, F. S., & Jenekhe, S. A. (2011) · Chemistry of Materials · doi:10.1021/cm202247a · Cited by 81
Kim, J., Lim, B., Baeg, K., Noh, Y., Khim, D., Jeong, H., Yun, J.-M., & Kim, D. (2011) · Chemistry of Materials · doi:10.1021/cm2021802 · Cited by 72
Ha, T., Sonar, P. M., Cobb, B., & Dodabalapur, A. (2011) · Organic Electronics · doi:10.1016/j.orgel.2011.10.003 · Cited by 41
Self-citationZhang, G., Liu, K., Li, Y., & Yang, M. (2009) · Polymer International · doi:10.1002/pi.2576 · Cited by 39
Lim, B., Yeo, J., Khim, D., & Kim, D. (2011) · Macromolecular Rapid Communications · doi:10.1002/marc.201100327 · Cited by 30
Wang, S., Tang, J., Zhao, L., Png, R., Wong, L., Chia, P., Chan, H. S. O., Ho, P. K. H., & Chua, L. (2008) · Applied Physics Letters · doi:10.1063/1.3001574 · Cited by 23
Self-citation
Research works printed but not linked: 3
- Bijleveld, 2011, J. Mater. Chem., 21, 9424
- Sonar, 2012, J. Mater. Chem., 22, 4225
- Kline, 2006, Polym. Rev., 46, 27
Cited by
Sorted by citations
Nielsen, C. B. O., Turbiez, M. G. R., & McCulloch, I. A. (2012) · Advanced Materials · doi:10.1002/adma.201201795 · Cited by 894
Li, Y., Sonar, P. M., Murphy, L., & Hong, W. L. (2013) · Energy & Environmental Science · doi:10.1039/c3ee00015j · Cited by 732
Self-citationYi, Z., Wang, S., & Liu, Y. (2015) · Advanced Materials · doi:10.1002/adma.201500401 · Cited by 404
Biodegradable Materials and Green Processing for Green Electronics
Li, W., Liu, Q., Zhang, Y., Li, C., He, Z., Choy, W. C. H., Low, P. J., Sonar, P. M., & Kyaw, A. K. K. (2020) · Advanced Materials · doi:10.1002/adma.202001591 · Cited by 403
Self-citationRecent progress in porphyrin-based materials for organic solar cells
Mahmood, A., Hu, J.-Y., Xiao, B., Tang, A., Wang, X., & Zhou, E. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta06392c · Cited by 311
Metadata
- Authors
- Sonar, P., Zhuo, J.-M., Zhao, L.-H., Lim, K.-M., Chen, J., Rondinone, A. J., Singh, S. P., Chua, L.-L., Ho, P. K. H., & Dodabalapur, A.
- Affiliations
- Agency for Science, Technology and Research (SG)
- National University of Singapore (SG)
- Oak Ridge National Laboratory (US)
- Corresponding author
- Sonar, Prashant
- Chua, Lay-Lay
- ORCID
- Venue
- Journal of Materials Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 22
- Issue
- 33
- Pages
- 17284
- ISSN
- 0959-9428 (ISSN-L)
- 1364-5501
- OpenAlex
- W2135761533
- Cited by
- 57
- References
- 35
- Citations by year
- 2025: 1 · 2024: 2 · 2023: 1 · 2022: 5 · 2021: 1 · 2020: 4 · 2019: 3 · 2018: 3 · 2017: 4 · 2016: 5 · 2015: 10 · 2014: 10 · 2013: 5 · 2012: 3
- FWCI
- 5.73
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Materials Chemistry (publishedVersion)
- National University of Singapore (submittedVersion)
- Funders
- Institute of Materials Research and Engineering
- Oak Ridge National Laboratory
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Electronics and Photovoltaics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Light-Emitting Diodes Research
- Physical Sciences › Materials Science › Polymers and Plastics › Conducting polymers and applications
- Keywords
- diketopyrrolopyrrole, donor-acceptor polymers, low band gap polymers, organic thin-film transistors, hole mobility, UV-Vis-NIR absorption, ionization potential, annealing, crystallinity, organic electronics
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
