Polyaniline–MnO2 coaxial nanofiber with hierarchical structure for high-performance supercapacitors
Abstract
We demonstrated the facile loading of ultrafine and loosened K-birnessite MnO2 floccules on the surface of polyaniline (PANI) nanofibers by simply soaking the polyaniline nanofibers in a KMnO4 aqueous solution for electrochemical energy storage applications. The as-prepared PANI–MnO2 coaxial nanofibers with optimal composition, when applied as an electrode, exhibited a high specific capacitance (383 F g−1 at 0.5 A g−1) with good rate and cycling stability in 1 M Na2SO4 aqueous solution. Such intriguing electrochemical performance is mainly attributed to the synergistic effects of the combined pseudo-capacitive contributions from the core and shell. The present findings promoted the development of advanced electrode materials, exhibiting huge potential for supercapacitors.
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The stability of the D-MoS2-PANI aerogel is higher than that of polyaniline-MnO2 coaxial nanofiber (75.5% retention after 2000 cycles) and coaxial PANI/TiN/PANI nanotube (83% retention after 3000 cycles).
“the stability of D-MoS2-PANI aerogel is higher than that of many previous PANI based hybrid electrodes, such as polyaniline-MnO2 coaxial nanofiber[28] (75.5% retention after 2000 cycle) and coaxial PANI/TiN/PANI nanotube[29] (83% retention after 3000 cycle).”
From Engineering of MoS<sub>2</sub> Quantum Dots/PANI Aerogel for High Performance Supercapaciator (2019) · cites this paper as [28]
The electrochemical reaction provides more paths for insertion and extraction of ions within the PANI nanowire arrays.
“the electrochemical reaction provides more paths for insertion and extraction of ions within the PANI nanowire arrays.[28]”
From Engineering of MoS<sub>2</sub> Quantum Dots/PANI Aerogel for High Performance Supercapaciator (2019) · cites this paper as [28]
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- Authors
- Jiang, H., Ma, J., & Li, C.
- Affiliations
- East China University of Science and Technology (CN)
- Nanyang Technological University (SG)
- Corresponding author
- Li, Chunzhong
- Venue
- Journal of Materials Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 22
- Issue
- 33
- Pages
- 16939
- ISSN
- 0959-9428 (ISSN-L)
- 1364-5501
- OpenAlex
- W2141325582
- Cited by
- 171
- References
- 17
- Citations by year
- 2026: 2 · 2025: 6 · 2024: 3 · 2023: 12 · 2022: 4 · 2021: 12 · 2020: 10 · 2019: 17 · 2018: 12 · 2017: 13 · 2016: 18 · 2015: 21 · 2014: 25 · 2013: 15 · 2012: 1
- FWCI
- 7.65
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Materials Chemistry (publishedVersion)
- DR-NTU (Nanyang Technological University) (submittedVersion)
- Funders
- National Natural Science Foundation of China
- Fundamental Research Funds for the Central Universities
- Topics
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Supercapacitor Materials and Fabrication
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced battery technologies research
- Physical Sciences › Materials Science › Polymers and Plastics › Conducting polymers and applications
- Keywords
- polyaniline, manganese dioxide, coaxial nanofibers, supercapacitors, manganese oxide, specific capacitance, pseudocapacitance, hierarchy, electrode materials, cycling stability
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