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Three-dimensional B,N-doped graphene foam as a metal-free catalyst for oxygen reduction reaction

Xue, Yuhua, Yu, Dingshan, Dai, Liming, Wang, Ruigang, Li, Dingqiang, Roy, Ajit, Lu, Fan, Chen, Hao, Liu, Yong, Qu, Jia·2013·Physical Chemistry Chemical Physics

Abstract

Using a modified chemical vapor deposition (CVD) method, we have prepared a class of new graphene foams (GFs) doped with nitrogen, boron or both. Nitrogen-doped graphene foams (N-GFs) with a nitrogen doping level of 3.1 atom% were prepared by CVD of CH4 in the presence of NH3 while boron-doped graphene foams (B-GFs) with a boron doping level of 2.1 atom% were produced by using toluene and triethyl borate as a carbon and a boron source. On the other hand, graphene foams co-doped with nitrogen (4.5 atom%) and boron (3 atom%) (BN-GFs) were prepared by CVD using melamine diborate as the precursor. In all cases, scanning electron microscope (SEM) images revealed well-defined foam-like microstructures, while electrochemical measurements showed much higher electrocatalytic activities toward oxygen reduction reaction for the doped graphene foams than their undoped counterparts.

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Metadata

Authors
Xue, Y., Yu, D., Dai, L., Wang, R., Li, D., Roy, A., Lu, F., Chen, H., Liu, Y., & Qu, J.
Venue
Physical Chemistry Chemical Physics
Published
2013
Volume
15
Issue
29
Pages
12220
ISSN
  • 1463-9076 (ISSN-L)
  • 1463-9084
OpenAlex
W2166842292
Cited by
314
References
3
FWCI
12.86
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Three-dimensional B,N-doped graphene foam as a metal-free catalyst for oxygen reduction reaction. https://app.cochat.ai/papers/10.1039/c3cp51942b
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Xue, Y., Yu, D., Dai, L., Wang, R., Li, D., Roy, A., Lu, F., Chen, H., Liu, Y., & Qu, J. (2013). Three-dimensional B,N-doped graphene foam as a metal-free catalyst for oxygen reduction reaction. Physical Chemistry Chemical Physics. https://doi.org/10.1039/c3cp51942b

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