The DOI matches its Crossref record; 228 of the 228 references it cites were found in a registry or an index.
Synthesis of non-siliceous mesoporous oxides
Abstract
Mesoporous non-siliceous oxides have attracted great interest due to their unique properties and potential applications. Since the discovery of mesoporous silicates in 1990s, organic-inorganic assembly processes by using surfactants or block copolymers as soft templates have been considered as a feasible path for creating mesopores in metal oxides. However, the harsh sol-gel conditions and low thermal stabilities have limited the expansion of this method to various metal oxide species. Nanocasting, using ordered mesoporous silica or carbon as a hard template, has provided possibilities for preparing novel mesoporous materials with new structures, compositions and high thermal stabilities. This review concerns the synthesis, composition, and parameter control of mesoporous non-siliceous oxides. Four synthesis routes, i.e. soft-templating (surfactants or block copolymers as templates), hard-templating (mesoporous silicas or carbons as sacrificial templates), colloidal crystal templating (3-D ordered colloidal particles as a template), and super lattice routes, are summarized in this review. Mesoporous metal oxides with different compositions have different properties. Non-siliceous mesoporous oxides are comprehensively described, including a discussion of constituting elements, synthesis, and structures. General aspects concerning pore size control, atomic scale crystallinity, and phase control are also reviewed.
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Hierarchically porous materials: synthesis strategies and structure design
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Metadata
- Authors
- Gu, D., & Schüth, F.
- Venue
- Chem. Soc. Rev.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2014
- Volume
- 43
- Issue
- 1
- Pages
- 313-344
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W2083725169
- Cited by
- 584
- References
- 228
- FWCI
- 2.67
- Type
- journal article
- Language
- en
- Open access
- closed
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