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Noble metal-free Ni(OH)2–g-C3N4 composite photocatalyst with enhanced visible-light photocatalytic H2-production activity
Abstract
Ni(OH)2-modified graphitic carbon nitride (Ni(OH)2–g-C3N4) composite photocatalysts were prepared by a simple precipitation method using g-C3N4 as support and nickel nitrate as precursor. The effect of Ni(OH)2 content on the rate of visible-light photocatalytic H2-production was studied for a series of Ni(OH)2–g-C3N4 composite samples in triethanolamine aqueous solutions. The results demonstrated that Ni(OH)2 was an efficient co-catalyst for the photocatalytic H2 production of g-C3N4. The optimal Ni(OH)2 loading was found to be 0.5 mol%, giving a H2-production rate of 7.6 μmol h−1 (with an apparent quantum efficiency (QE) of 1.1% at 420 nm), which approached that of optimal 1.0 wt% Pt/g-C3N4 (8.2 μmol h−1). This work showed the possibility for the utilization of low cost Ni(OH)2 as a substitute for noble metals (such as Pt) in the photocatalytic H2 production for g-C3N4.
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Self-citationXiang, Q., Yu, J., & Jaroniec, M. (2012) · Journal of the American Chemical Society · doi:10.1021/ja302846n · Cited by 2,360
Self-citationEnhanced TiO2 photocatalysis by Cu in hydrogen production from aqueous methanol solution
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Cited by
Ong, W.-J., Tan, L.-L., Ng, Y. H., Yong, S.-T., & Chai, S.-P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00075 · Cited by 7,147
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Self-citationEmerging Cocatalysts on g‐C3N4 for Photocatalytic Hydrogen Evolution
Zhu, Q., Xu, Z., Qiu, B., Xing, M., & Zhang, J. (2021) · Small · doi:10.1002/smll.202101070 · Cited by 380
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Metadata
- Authors
- Yu, J., Wang, S., Cheng, B., Lin, Z., & Huang, F.
- Venue
- Catalysis Science & Technology
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2013
- Volume
- 3
- Issue
- 7
- Pages
- 1782
- ISSN
- 2044-4753 (ISSN-L)
- 2044-4761
- OpenAlex
- W2005144971
- Cited by
- 456
- References
- 7
- FWCI
- 13.83
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yu, J., Wang, S., Cheng, B., Lin, Z., & Huang, F. (2013). Noble metal-free Ni(OH)2–g-C3N4 composite photocatalyst with enhanced visible-light photocatalytic H2-production activity. Catalysis Science & Technology. https://doi.org/10.1039/c3cy20878h
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