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Structure–properties relationship of fatty acid-based thermoplastics as synthetic polymer mimics
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Nowadays the use of vegetable oils as polymer precursors is the subject of growing interest in the academic and industrial communities. Many synthetic pathways can be pursued from natural vegetable oils to yield different functionalized derivatives – also called synthons – and polymers, such as polyesters, polyurethanes, polyamides, etc. Herein, we widely overview recent progress in the preparation of vegetable oil-based thermoplastic polymers and, more precisely, thermoplastic polyesters and polyurethanes. Extra focus is also placed on the synthesis sustainability of these polymeric materials via atom efficient techniques, “green” catalyses and processes. The achievable bio-sourced polymers cover a wide range of thermo-mechanical properties that can respond to most of the current applications of synthetic polymers.
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“Fatty acids obtained from transesterification of plant oils have been a long-standing biofeedstock for polymer production.25,98”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [98]
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Metadata
- Authors
- Maisonneuve, L., Lebarbé, T., Grau, E., & Cramail, H.
- Affiliations
- Centre National de la Recherche Scientifique (FR)
- Corresponding author
- Cramail, Henri
- ORCID
- Cramail, Henri
- Venue
- Polymer Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2013
- Volume
- 4
- Issue
- 22
- Pages
- 5472
- ISSN
- 1759-9954 (ISSN-L)
- 1759-9962
- OpenAlex
- W2025548396
- Cited by
- 220
- References
- 240
- Citations by year
- 2026: 7 · 2025: 8 · 2024: 11 · 2023: 8 · 2022: 12 · 2021: 17 · 2020: 17 · 2019: 19 · 2018: 22 · 2017: 18 · 2016: 26 · 2015: 22 · 2014: 29 · 2013: 4
- FWCI
- 10.30
- Type
- journal article
- Language
- en
- Open access
- green
- hal.science
- Licence
- other-oa
- Locations
- Polymer Chemistry (publishedVersion)
- HAL (submittedVersion, other-oa)
- Oskar-Bordeaux (Universite de Bordeaux) (submittedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer Science and PVC
- Keywords
- thermoplastic polyesters, thermoplastic polyurethane, structure-property relationships, bio-based polymers, atom economy, green catalysis, thermomechanical properties
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