Cited by 220biodegradable polymer synthesis and propertiesPolymer composites and self-healingPolymer Science and PVC

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Structure–properties relationship of fatty acid-based thermoplastics as synthetic polymer mimics

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Maisonneuve, Lise, Lebarbé, Thomas, Grau, Etienne, Cramail, Henri·2013·Polymer Chemistry

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Abstract

Nowadays the use of vegetable oils as polymer precursors is the subject of growing interest in the academic and industrial communities. Many synthetic pathways can be pursued from natural vegetable oils to yield different functionalized derivatives – also called synthons – and polymers, such as polyesters, polyurethanes, polyamides, etc. Herein, we widely overview recent progress in the preparation of vegetable oil-based thermoplastic polymers and, more precisely, thermoplastic polyesters and polyurethanes. Extra focus is also placed on the synthesis sustainability of these polymeric materials via atom efficient techniques, “green” catalyses and processes. The achievable bio-sourced polymers cover a wide range of thermo-mechanical properties that can respond to most of the current applications of synthetic polymers.

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Authors: Maisonneuve, L., Lebarbé, T., Grau, E., & Cramail, H.
Affiliations: Centre National de la Recherche Scientifique (FR)
Corresponding author: Cramail, Henri
ORCID: Cramail, Henri
Venue: Polymer Chemistry
Publisher: Royal Society of Chemistry (RSC)
Published: 2013
Volume: 4
Issue: 22
Pages: 5472
ISSN: 1759-9954 (ISSN-L)
1759-9962
DOI: 10.1039/c3py00791j
OpenAlex: W2025548396
Cited by: 220
References: 240
Citations by year: 2026: 7 · 2025: 8 · 2024: 11 · 2023: 8 · 2022: 12 · 2021: 17 · 2020: 17 · 2019: 19 · 2018: 22 · 2017: 18 · 2016: 26 · 2015: 22 · 2014: 29 · 2013: 4
FWCI: 10.30
Type: journal article
Language: en
Open access: green
hal.science
Licence: other-oa
Locations: Polymer Chemistry (publishedVersion)
HAL (submittedVersion, other-oa)
Oskar-Bordeaux (Universite de Bordeaux) (submittedVersion)
Topics: Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
Physical Sciences › Materials Science › Polymers and Plastics › Polymer Science and PVC
Keywords: thermoplastic polyesters, thermoplastic polyurethane, structure-property relationships, bio-based polymers, atom economy, green catalysis, thermomechanical properties

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Structure–properties relationship of fatty acid-based thermoplastics as synthetic polymer mimics

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