Cited by 116Electrophoretic Deposition in Materials ScienceBone Tissue Engineering MaterialsSurface Treatment and Coatings

Electrophoretic deposition of nanostructured-TiO2/chitosan composite coatings on stainless steel

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Cordero-Arias, L., Cabanas-Polo, S., Gao, Haoxiang, Gilabert, J., Sanchez, E., Roether, J. A., Schubert, D. W., Virtanen, S. +1 more·2013·RSC Advances

Abstract

Novel chitosan composite coatings containing titania nanoparticles (n-TiO2) for biomedical applications were developed by electrophoretic deposition (EPD) from ethanol–water suspensions. The optimal ethanol–water ratio was studied in order to avoid bubble formation during the EPD process and to ensure homogeneous coatings. Different n-TiO2 contents (0.5–10 g L−1) were studied for a fixed chitosan concentration (0.5 g L−1) and the properties of the electrophoretic coatings obtained were characterized. Coating composition was analyzed by thermogravimetric analysis (TG), Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) analysis. Scanning electron microscopy (SEM) was employed to study both the surface and the cross section morphology of the coatings, and the thicknesses (2–6 μm) of the obtained coatings were correlated with the initial ceramic content. Contact angle measurements, as a preliminary study to predict hypothetic protein attachment on the coatings, were performed for different samples and the influence of a second chitosan layer on top of the coatings was also tested. Finally, the electrochemical behavior of the coatings, evaluated by polarization curves in DMEM at 37 °C, was studied in order to assess the corrosion resistance provided by the n-TiO2/chitosan coatings.

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Authors
Cordero-Arias, L., Cabanas-Polo, S., Gao, H., Gilabert, J., Sanchez, E., Roether, J. A., Schubert, D. W., Virtanen, S., & Boccaccini, A. R.
Affiliations
  • Friedrich-Alexander-Universität Erlangen-Nürnberg (DE)
  • Imperial College London (GB)
  • Universitat Jaume I (ES)
Venue
RSC Advances
Published
2013
Volume
3
Issue
28
Pages
11247
ISSN
2046-2069 (ISSN-L)
OpenAlex
W1980948789
Cited by
116
References
71
Citations by year
2026: 5 · 2025: 9 · 2024: 12 · 2023: 11 · 2022: 9 · 2021: 11 · 2020: 14 · 2019: 8 · 2018: 5 · 2017: 10 · 2016: 5 · 2015: 9 · 2014: 7 · 2013: 1
FWCI
4.39
Type
journal article
Language
en
Open access
Locations
  • RSC Advances (publishedVersion)
  • Repositori UJI (Universitat Jaume I) (acceptedVersion)
  • LA Referencia (Red Federada de Repositorios Institucionales de Publicaciones Científicas) (submittedVersion, public-domain)
Funders
Deutscher Akademischer Austauschdienst
Topics
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Electrophoretic Deposition in Materials Science
  • Physical Sciences › Engineering › Biomedical Engineering › Bone Tissue Engineering Materials
  • Physical Sciences › Engineering › Mechanical Engineering › Surface Treatment and Coatings
Keywords
electrophoretic deposition, titanium dioxide nanoparticles, chitosan, composite coatings, stainless steel, bubble formation, coating morphology, protein adsorption, contact angle, corrosion resistance, biomedical coatings

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