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A rapid method to estimate the concentration of citrate capped silver nanoparticles from UV-visible light spectra

Open access
Paramelle, D., Sadovoy, A., Gorelik, S., Free, P., Hobley, J., Fernig, D. G.·2014·The Analyst

Abstract

We present a generalized table of extinction coefficient data for silver nanoparticles from 8 to 100 nm. This table allows for easy and quick estimation of the concentration and size of modified and mono-dispersed silver nanoparticles from their optical spectra. We obtained data by determining the silver content of citrate-stabilised silver nanoparticles using sodium cyanide to dissolve the nanoparticles, and measuring solution conductivity with a pH meter and a cyanide-ion selective electrode. The quantification of the silver ion concentration enabled the calculation of extinction coefficients. Experimentally calculated extinction coefficients, in the current work, are in good agreement with collated literature values measured by different authors with non-standardized methodology and each for a limited range of particle size. They are also in good agreement with our theoretical calculations using Mie theory. Thus, we provide a highly standardized and comprehensive tabulated reference data-set.

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Metadata

Authors
Paramelle, D., Sadovoy, A., Gorelik, S., Free, P., Hobley, J., & Fernig, D. G.
Venue
The Analyst
Published
2014-07-01
Volume
139
Issue
19
Pages
4855
ISSN
  • 0003-2654 (ISSN-L)
  • 1364-5528
OpenAlex
W1994480476
Cited by
800
References
0
FWCI
9.31
Type
journal article
Language
en
Open access
bronze

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CoChat. (2026). Citation check: A rapid method to estimate the concentration of citrate capped silver nanoparticles from UV-visible light spectra. https://app.cochat.ai/papers/10.1039/c4an00978a
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Paramelle, D., Sadovoy, A., Gorelik, S., Free, P., Hobley, J., & Fernig, D. G. (2014). A rapid method to estimate the concentration of citrate capped silver nanoparticles from UV-visible light spectra. The Analyst. https://doi.org/10.1039/c4an00978a

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.