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Are Zr6-based MOFs water stable? Linker hydrolysis vs. capillary-force-driven channel collapse
Abstract
Metal-organic frameworks (MOFs) built up from Zr6-based nodes and multi-topic carboxylate linkers have attracted attention due to their favourable thermal and chemical stability. However, the hydrolytic stability of some of these Zr6-based MOFs has recently been questioned. Herein we demonstrate that two Zr6-based frameworks, namely UiO-67 and NU-1000, are stable towards linker hydrolysis in H2O, but collapse during activation from H2O. Importantly, this framework collapse can be overcome by utilizing solvent-exchange to solvents exhibiting lower capillary forces such as acetone.
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Horike, S., Shimomura, S., & Kitagawa, S. (2009) · Nature Chemistry · doi:10.1038/nchem.444 · Cited by 2,486
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Younas, M., Rezakazemi, M., Daud, M., Wazir, M. B., Ahmad, S., Ullah, N., Inamuddin, & Ramakrishna, S. (2020) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2020.100849 · Cited by 421
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Lv, X.-L., Yuan, S., Xie, L.-H., Darke, H. F., Chen, Y., He, T., Dong, C., Wang, B., Zhang, Y.-Z., Li, J.-R., et al. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b02947 · Cited by 322
Hod, I., Deria, P., Bury, W., Mondloch, J. E., Kung, C.-W., So, M., Sampson, M. D., Peters, A. W., Kubiak, C. P., Farha, O. K., et al. (2015) · Nature Communications · doi:10.1038/ncomms9304 · Cited by 290
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Metadata
- Authors
- Mondloch, J. E., Katz, M. J., Planas, N., Semrouni, D., Gagliardi, L., Hupp, J. T., & Farha, O. K.
- Venue
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2014-06-30
- Volume
- 50
- Issue
- 64
- Pages
- 8944
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W1992907854
- Cited by
- 336
- References
- 1
- FWCI
- 12.42
- Type
- journal article
- Language
- en
- Open access
- closed
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- Mondloch, J. E., Katz, M. J., Planas, N., Semrouni, D., Gagliardi, L., Hupp, J. T., & Farha, O. K. (2014). Are Zr6-based MOFs water stable? Linker hydrolysis vs. capillary-force-driven channel collapse. Chemical Communications. https://doi.org/10.1039/c4cc02401j
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