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Are Zr6-based MOFs water stable? Linker hydrolysis vs. capillary-force-driven channel collapse
Abstract
Metal-organic frameworks (MOFs) built up from Zr6-based nodes and multi-topic carboxylate linkers have attracted attention due to their favourable thermal and chemical stability. However, the hydrolytic stability of some of these Zr6-based MOFs has recently been questioned. Herein we demonstrate that two Zr6-based frameworks, namely UiO-67 and NU-1000, are stable towards linker hydrolysis in H2O, but collapse during activation from H2O. Importantly, this framework collapse can be overcome by utilizing solvent-exchange to solvents exhibiting lower capillary forces such as acetone.
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Horike, S., Shimomura, S., & Kitagawa, S. (2009) · Nature Chemistry · doi:10.1038/nchem.444 · Cited by 2,486
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Metadata
- Authors
- Mondloch, J. E., Katz, M. J., Planas, N., Semrouni, D., Gagliardi, L., Hupp, J. T., & Farha, O. K.
- Venue
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2014-06-30
- Volume
- 50
- Issue
- 64
- Pages
- 8944
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W1992907854
- Cited by
- 336
- References
- 1
- FWCI
- 12.42
- Type
- journal article
- Language
- en
- Open access
- closed
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