Structure, function, self-assembly, and applications of bottlebrush copolymers

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Nanocomposites with Polymer Grafted Nanoparticles

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Stimuli-responsive molecular brushes

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Broad-wavelength-range chemically tunable block-copolymer photonic gels

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Synthesis of Molecular Brushes by “Grafting onto” Method: Combination of ATRP and Click Reactions

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Adaptive and responsive surfaces through controlled reorganization of interfacial polymer layers

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In Pursuit of Zero: Polymer Brushes that Resist the Adsorption of Proteins

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The effects of polymeric nanostructure shape on drug delivery

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Polymer brush coatings for combating marine biofouling

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Efficient Synthesis of Narrowly Dispersed Brush Copolymers and Study of Their Assemblies: The Importance of Side Chain Arrangement

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Well-defined graft copolymers: from controlled synthesis to multipurpose applications

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Antimicrobial Polymers Prepared by ROMP with Unprecedented Selectivity: A Molecular Construction Kit Approach

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Rapid self-assembly of brush block copolymers to photonic crystals

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Visualization of MacromoleculesA First Step to Manipulation and Controlled Response

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Molecular Bottlebrushes

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Adsorption-induced scission of carbon–carbon bonds

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A Convergent Synthetic Platform for Single-Nanoparticle Combination Cancer Therapy: Ratiometric Loading and Controlled Release of Cisplatin, Doxorubicin, and Camptothecin

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Core-Clickable PEG-Branch-Azide Bivalent-Bottle-Brush Polymers by ROMP: Grafting-Through and Clicking-To

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Drug-Loaded, Bivalent-Bottle-Brush Polymers by Graft-through ROMP

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Efficient Synthesis of Narrowly Dispersed Brush Polymers via Living Ring-Opening Metathesis Polymerization of Macromonomers

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Synthesis of Polystyrene−Polylactide Bottlebrush Block Copolymers and Their Melt Self-Assembly into Large Domain Nanostructures

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Synthesis of Isocyanate-Based Brush Block Copolymers and Their Rapid Self-Assembly to Infrared-Reflecting Photonic Crystals

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Precisely Tunable Photonic Crystals From Rapidly Self‐Assembling Brush Block Copolymer Blends

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Highly Efficient “Grafting onto” a Polypeptide Backbone Using Click Chemistry

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Aqueous Self-Assembly of Giant Bottlebrush Block Copolymer Surfactants as Shape-Tunable Building Blocks

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Well-Defined Organic Nanotubes from Multicomponent Bottlebrush Copolymers

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Tandem Synthesis of Core−Shell Brush Copolymers and Their Transformation to Peripherally Cross-Linked and Hollowed Nanostructures

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On the shape of bottle-brush macromolecules: Systematic variation of architectural parameters

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Linear Rheological Response of a Series of Densely Branched Brush Polymers

Hu, M., Xia, Y., McKenna, G. B., Kornfield, J. A., & Grubbs, R. H. (2011) · Macromolecules · doi:10.1021/ma2009673 · Cited by 215

Efficient synthesis of multifunctional polymers via thiol–epoxy “click” chemistry

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Single Molecule Rod−Globule Phase Transition for Brush Molecules at a Flat Interface

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Large Pore Size Nanoporous Materials from the Self-Assembly of Asymmetric Bottlebrush Block Copolymers

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Synthesis of High Molecular Weight Comb Block Copolymers and Their Assembly into Ordered Morphologies in the Solid State

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Synthesis of Molecular Brushes with Gradient in Grafting Density by Atom Transfer Polymerization

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Synthesis of Ultralarge Molecular Weight Bottlebrush Polymers Using Grubbs' Catalysts

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Dynamic Cylindrical Assembly of Triblock Copolymers by a Hierarchical Process of Covalent and Supramolecular Interactions

Li, Z., Ma, J., Lee, N. S., & Wooley, K. L. (2011) · Journal of the American Chemical Society · doi:10.1021/ja109191z · Cited by 179

Small-Angle Neutron Scattering Analysis of Bottlebrush Polymers Prepared via Grafting-Through Polymerization

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Low Polydispersity Star Polymers via Cross-Linking Macromonomers by ATRP

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Synthesis of Hetero-Grafted Amphiphilic Diblock Molecular Brushes and Their Self-Assembly in Aqueous Medium

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Self-Assembly of Symmetric Brush Diblock Copolymers

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Facile syntheses of cylindrical molecular brushes by a sequential RAFT and ROMP “grafting‐through” methodology

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Surface Properties of Bottlebrush Polymer Thin Films

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Shaped Hairy Polymer Nanoobjects

Chen, Y. (2012) · Macromolecules · doi:10.1021/ma201495m · Cited by 139

Facile One-Pot Synthesis of Brush Polymers through Tandem Catalysis Using Grubbs' Catalyst for Both Ring-Opening Metathesis and Atom Transfer Radical Polymerizations

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Molecular Weight Dependence of Zero-Shear Viscosity in Atactic Polypropylene Bottlebrush Polymers

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Synthesis of Comb Block Copolymers by ROMP, ATRP, and ROP and Their Assembly in the Solid State

Runge, M. B., Dutta, S., & Bowden, N. B. (2005) · Macromolecules · doi:10.1021/ma052012g · Cited by 124

“Brush-First” Method for the Parallel Synthesis of Photocleavable, Nitroxide-Labeled Poly(ethylene glycol) Star Polymers

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General Synthetic Route to Cell-Permeable Block Copolymers via ROMP

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Nanoscopic Cylindrical Dual Concentric and Lengthwise Block Brush Terpolymers as Covalent Preassembled High-Resolution and High-Sensitivity Negative-Tone Photoresist Materials

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Bottle-brush macromolecules in solution: Comparison between results obtained from scattering experiments and computer simulations

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Solution Behavior of Temperature‐Responsive Molecular Brushes Prepared by ATRP

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On the Self-Assembly of Brush Block Copolymers in Thin Films

Hong, S. W., Gu, W., Huh, J., Sveinbjörnsson, B. R., Jeong, G., Grubbs, R. H., & Russell, T. P. (2013) · ACS Nano · doi:10.1021/nn402639g · Cited by 107

Tension Amplification in Molecular Brushes in Solutions and on Substrates

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pH-Sensitive brush polymer-drug conjugates by ring-opening metathesis copolymerization

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Polymeric micelles formed by polypeptide graft copolymer and its mixtures with polypeptide block copolymer

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EPR Study of Spin Labeled Brush Polymers in Organic Solvents

Xia, Y., Li, Y., Burts, A. O., Ottaviani, M. F., Tirrell, D. A., Johnson, J. A., Turro, N. J., & Grubbs, R. H. (2011) · Journal of the American Chemical Society · doi:10.1021/ja2085349 · Cited by 91

Highly Ordered Dielectric Mirrors via the Self-Assembly of Dendronized Block Copolymers

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Ring-Opening Metathesis Polymers for Biodetection and Signal Amplification: Synthesis and Self-Assembly

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High‐Contrast Fluorescence Imaging of Tumors In Vivo Using Nanoparticles of Amphiphilic Brush‐Like Copolymers Produced by ROMP

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Self-Assembly of Block Copolymers for Photonic-Bandgap Materials

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Synthesis of Well-Defined ω-Oxanorbornenyl Poly(ethylene oxide) Macromonomers via Click Chemistry and Their Ring-Opening Metathesis Polymerization

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Macromonomers: A new class of polymeric intermediates in macromolecular synthesis - II - homo- and copolymerization

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Synthesis and Melt Self-Assembly of PS–PMMA–PLA Triblock Bottlebrush Copolymers

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Synthesis of well-defined multigraft copolymers

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Molecular Design of Liquid Crystalline Brush-Like Block Copolymers for Magnetic Field Directed Self-Assembly: A Platform for Functional Materials

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Functionalized Molecular Bottlebrushes

Gadwal, I. M. S., Rao, J., Baettig, J., & Khan, A. (2013) · Macromolecules · doi:10.1021/ma402259q · Cited by 66

Hyperbranched Fluoropolymers and their Hybridization into Complex Amphiphilic Crosslinked Copolymer Networks

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One‐ and Two‐Component Bottle‐Brush Polymers: Simulations Compared to Theoretical Predictions

Hsu, H., Paul, W., & Binder, K. (2007) · Macromolecular Theory and Simulations · doi:10.1002/mats.200700031 · Cited by 65

Understanding the Multiple Length Scales Describing the Structure of Bottle‐brush Polymers by Monte Carlo Simulation Methods

Hsu, H., Paul, W., & Binder, K. (2011) · Macromolecular Theory and Simulations · doi:10.1002/mats.201000092 · Cited by 63

Investigation of the Assembly of Comb Block Copolymers in the Solid State

Runge, M. B., Lipscomb, C. E., Ditzler, L. R., Mahanthappa, M. K., Tivanski, A. V., & Bowden, N. B. (2008) · Macromolecules · doi:10.1021/ma8009323 · Cited by 62

Synthesis and Direct Visualization of Dumbbell-Shaped Molecular Brushes

Li, A., Li, Z., Zhang, S., Sun, G., Policarpio, D. M., & Wooley, K. L. (2011) · ACS Macro Letters · doi:10.1021/mz200184f · Cited by 61

Synthesis of Segmented Polylactide Molecular Brushes and Their Transformation to Open-End Nanotubes

Huang, K., Canterbury, D. P., & Rzayev, J. (2010) · Macromolecules · doi:10.1021/ma100971w · Cited by 60

Brush Polymers Containing Semiconducting Polyene Backbones: Graft-Through Synthesis via Cyclopolymerization and Conformational Analysis on the Coil-to-Rod Transition

Kang, E.-H., Lee, I., & Choi, T. (2012) · ACS Macro Letters · doi:10.1021/mz3002897 · Cited by 59

De Novo Synthesis and Cellular Uptake of Organic Nanocapsules with Tunable Surface Chemistry

Huang, K., Jacobs, A., & Rzayev, J. (2011) · Biomacromolecules · doi:10.1021/bm200394t · Cited by 58

Brush‐First Synthesis of Core‐Photodegradable Miktoarm Star Polymers via ROMP: Towards Photoresponsive Self‐Assemblies

Burts, A. O., Gao, A. X., & Johnson, J. A. (2013) · Macromolecular Rapid Communications · doi:10.1002/marc.201300618 · Cited by 57

Thin Film Phase Behavior of Bottlebrush/Linear Polymer Blends

Mitra, I., Li, X., Pesek, S. L., Makarenko, B., Lokitz, B. S., Uhrig, D. W., Ankner, J. F., Verduzco, R., & Stein, G. E. (2014) · Macromolecules · doi:10.1021/ma501070w · Cited by 57

DNA-Grafted Polypeptide Molecular Bottlebrush Prepared via Ring-Opening Polymerization and Click Chemistry

Chen, P., Li, C., Liu, D., et al. (2012) · Macromolecules · doi:10.1021/ma302233m · Cited by 56

Toroidal structures from brush amphiphiles

Luo, H., Santos, J. L., & Herrera‐Alonso, M. (2013) · Chemical Communications · doi:10.1039/c3cc46834h · Cited by 56

Bond Tension in Tethered Macromolecules

Sheiko, S. S., Panyukov, S., & Rubinstein, M. (2011) · Macromolecules · doi:10.1021/ma200328h · Cited by 56

Synthesis of Poly(vinyl acetate) Molecular Brushes by a Combination of Atom Transfer Radical Polymerization (ATRP) and Reversible Addition−Fragmentation Chain Transfer (RAFT) Polymerization

Nese, A., Kwak, Y., Nicolaÿ, R., Barrett, M., Sheiko, S. S., & Matyjaszewski, K. A. (2010) · Macromolecules · doi:10.1021/ma1004698 · Cited by 55

Synthesis of novel cylindrical bottlebrush polypseudorotaxane via inclusion complexation of high density poly(ε-caprolactone) bottlebrush polymer and α-cyclodextrins

Fu, Q., Ren, J. M., & Qiao, G. G. (2011) · Polymer Chemistry · doi:10.1039/c1py00362c · Cited by 52

Interplay between Liquid Crystalline Order and Microphase Segregation on the Self-Assembly of Side-Chain Liquid Crystalline Brush Block Copolymers

Deshmukh, P. H., Ahn, S., de Merxem, L. G., & Kasi, R. M. (2013) · Macromolecules · doi:10.1021/ma401448j · Cited by 48

Straightforward Access to Amphiphilic Dual Bottle Brushes by Combining RAFT, ATRP, and NMP Polymerization in One Sequence

Zehm, D., Laschewsky, A., Liang, H., et al. (2011) · Macromolecules · doi:10.1021/ma2015613 · Cited by 48

Influence of Side Chain Length on Fluorescence Intensity of ROMP‐Based Polymeric Nanoparticles and Their Tumor Specificity in In‐Vivo Tumor Imaging

Miki, K., Oride, K., Kimura, A., Kuramochi, Y., Matsuoka, H., Harada, H., Hiraoka, M., & Ohe, K. (2011) · Small · doi:10.1002/smll.201101637 · Cited by 38

Polymer bottlebrushes with a redox responsive backbone feel the heat: synthesis and characterization of dual responsive poly(ferrocenylsilane)s with PNIPAM side chains

Kutnyánszky, E., Hempenius, M. A., & Vancso, G. J. (2013) · Polymer Chemistry · doi:10.1039/c3py01095c · Cited by 36

Hierarchically Self-Assembled Photonic Materials from Liquid Crystalline Random Brush Copolymers

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Synthesis and Ring-Opening Metathesis Polymerization of Norbornene-Terminated Syndiotactic Polypropylene

Anderson‐Wile, A. M., Coates, G. W., Auriemma, F., Rosa, C. D., & Silvestre, A. (2012) · Macromolecules · doi:10.1021/ma301073s · Cited by 33

Synthesis of block polymer miktobrushes

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Flory Theorem for Structurally Asymmetric Mixtures

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Directing Self‐Assembly of Nanoscopic Cylindrical Diblock Brush Terpolymers into Films with Desired Spatial Orientations: Expansion of Chemical Composition Scope

Cho, S., Yang, F., Sun, G., Eller, M. J., Clark, C., Schweikert, E. A., Thackeray, J. W., Trefonas, P., & Wooley, K. L. (2013) · Macromolecular Rapid Communications · doi:10.1002/marc.201300845 · Cited by 21

Synthesis and Bulk Self-Assembly of Well-Defined Binary Graft Copolymers

Hou, C., Hu, J., Liu, G., Wang, J., Liu, F., Hu, H., Zhang, G., Zou, H., Tu, Y., & Liao, B. (2013) · Macromolecules · doi:10.1021/ma400179r · Cited by 21

Synthesis and applications of anisotropic nanoparticles with precisely defined dimensions

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