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Morphology-dependent surface chemistry and catalysis of CeO2nanocrystals
Abstract
Surface chemistry and catalysis over oxide nanocrystals with well-defined morphologies are emerging as a hot topic, and the relevant progress on CeO2 nanocrystals is critically reviewed. CeO2 nanocrystals expose morphology-dependent crystal planes on their surfaces, and CeO2 nanocrystal and metal/CeO2 nanocrystal catalysts exhibit morphology-dependent surface chemistry and catalysis. A comprehensive analysis of the published literature nicely correlates the surface chemistry and catalysis of CeO2 nanocrystal and metal/CeO2 nanocrystal catalysts with the surface composition/structure and oxygen vacancy structure of exposed CeO2 crystal planes. A concept of morphology engineering of oxide nanocrystals not only for the optimization of the catalytic performance but also for the fundamental understanding of the structure–activity relation and catalytic reaction mechanism is discussed.
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Cites
Chemistry and Properties of Nanocrystals of Different Shapes
Burda, C., Chen, X., Narayanan, R., & El-Sayed, M. A. (2005) · Chemical Reviews · doi:10.1021/cr030063a · Cited by 7,230
Cited by
Fundamentals and Catalytic Applications of CeO 2 -Based Materials
Montini, T., Melchionna, M., Monai, M., & Fornasiero, P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00603 · Cited by 2,766
Zhang, S., Xia, Z., Zou, Y., Cao, F., Liu, Y., Ma, Y., & Qu, Y. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b03217 · Cited by 304
Sun, H., Wang, H., & Qu, Z. (2023) · ACS Catalysis · doi:10.1021/acscatal.2c05168 · Cited by 298
Metadata
- Authors
- Huang, W., & Gao, Y.
- Venue
- Catal. Sci. Technol.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2014-06-25
- Volume
- 4
- Issue
- 11
- Pages
- 3772-3784
- ISSN
- 2044-4753 (ISSN-L)
- 2044-4761
- OpenAlex
- W2027097263
- Cited by
- 242
- References
- 1
- FWCI
- 9.23
- Type
- journal article
- Language
- en
- Open access
- closed
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