The DOI matches its Crossref record; 31 of the 31 references it cites were found in a registry or an index.
Interfacial Frustrated Lewis Pairs of CeO2 Activate CO2 for Selective Tandem Transformation of Olefins and CO2 into Cyclic Carbonates
Abstract
Effective activation of CO 2 is a prerequisite for efficient utilization of CO 2 in organic synthesis. Precisely controlling the interfacial events of solids shows potential for activation. Herein, defect-enriched CeO 2 with constructed interfacial frustrated Lewis pairs (FLPs, two adjacent Ce 3+ ···O 2– ) effectively activates CO 2 via the interactions between C/Lewis basic lattice O 2– and the two O atoms in CO 2 /two adjacent Lewis acidic Ce 3+ ions. Selective cyclic carbonate production from a catalytically tandem protocol of olefins and CO 2 is used to demonstrate FLP-inspired CO 2 activation.
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Fundamentals and Catalytic Applications of CeO 2 -Based Materials
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Using carbon dioxide as a building block in organic synthesis
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Oxygen Vacancy Clusters Promoting Reducibility and Activity of Ceria Nanorods
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Cited by
Zhao, X., Chang, G., Xu, H., Yao, Y., Dong, D., Yang, S., Tian, G., & Yang, X. (2024) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.3c18885 · Cited by 33
Hierarchical Amino-Functionalized Ionic Liquids@MOF Composite Gel for Catalytic Conversion of CO2
Dong, D., Zhao, X., Pu, C., Yao, Y., Zhao, B., Tian, G., Chang, G., & Yang, X. (2023) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.3c03923 · Cited by 17
Metadata
- Authors
- Zhang, S., Xia, Z., Zou, Y., Cao, F., Liu, Y., Ma, Y., & Qu, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-07-10
- Volume
- 141
- Issue
- 29
- Pages
- 11353-11357
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2957108895
- Cited by
- 304
- References
- 31
- FWCI
- 5.95
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhang, S., Xia, Z., Zou, Y., Cao, F., Liu, Y., Ma, Y., & Qu, Y. (2019). Interfacial Frustrated Lewis Pairs of CeO2 Activate CO2 for Selective Tandem Transformation of Olefins and CO2 into Cyclic Carbonates. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.9b03217
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