The DOI matches its Crossref record; 32 of the 32 references it cites were found in a registry or an index.
Ultrafast high-capacity NiZn battery with NiAlCo-layered double hydroxide
Abstract
High-performance, low-cost, safe and environmentally friendly batteries are important for portable electronics and electric vehicles. Here, we synthesized NiAlCo-layered double hydroxide (LDH) nanoplates attached to few-walled carbon nanotubes (NiAlCo LDH/CNT) as the cathode material of a rechargeable NiZn battery in aqueous alkaline electrolytes. The α-phase nickel hydroxide with ultrathin morphology and strong coupling to nanotubes afforded a cathode with a high capacity of ∼354 mA h g−1 and ∼278 mA h g−1 at current densities of 6.7 A g−1 and 66.7 A g−1, respectively. Al and Co co-doping is unique for stabilizing α-phase nickel hydroxide with only a small capacity loss of ∼6% over 2000 charge and discharge cycles at 66.7 A g−1. Rechargeable ultrafast NiZn batteries with NiAlCo LDH/CNT cathode and a zinc anode can deliver a cell voltage of ∼1.75 V, energy density of ∼274 W h kg−1 and power density of ∼16 kW kg−1 (based on active materials) with a charging time of <1 minute. The results open the possibility of ultrafast and safe batteries with high energy density.
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Metadata
- Authors
- Gong, M., Li, Y., Zhang, H., Zhang, B., Zhou, W., Feng, J., Wang, H., Liang, Y., Fan, Z., Liu, J., & Dai, H.
- Venue
- Energy & Environmental Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2014
- Volume
- 7
- Issue
- 6
- Pages
- 2025
- ISSN
- 1754-5692 (ISSN-L)
- 1754-5706
- OpenAlex
- W2156257100
- Cited by
- 309
- References
- 32
- FWCI
- 10.44
- Type
- journal article
- Language
- en
- Open access
- closed
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