The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Aqueous photoinduced living/controlled polymerization: tailoring for bioconjugation
Abstract
We report a photoinduced living polymerization technique able to polymerize a large range of monomers, including methacrylates, acrylates and acrylamides, in water and biological media as well as organic solvents. This polymerization technique employs ultra-low concentrations of a ruthenium-based photoredox catalyst (typically 1 ppm to monomers) and enables low energy visible LED light to afford well-defined polymers with narrow polydispersities (Mw/Mn < 1.3). In this paper, different parameters, including photocatalyst concentrations and solvent effects, were thoroughly investigated. In addition, successful polymerizations in biological media have been reported with good control of the molecular weights and molecular weight distributions (Mw/Mn < 1.4). Finally, protein–polymer bioconjugates using a “grafting from” approach were demonstrated using bovine serum albumin as a model biomacromolecule. The enzymatic bioactivity of the protein was demonstrated to be maintained using a standard assay.
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Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Cited by
Metal-Free Atom Transfer Radical Polymerization
Treat, N. J., Sprafke, H., Kramer, J. W., Clark, P. G., Barton, B. E., Read de Alaniz, J., Fors, B. P., & Hawker, C. J. (2014) · Journal of the American Chemical Society · doi:10.1021/ja510389m · Cited by 939
McKenzie, T. G., Fu, Q., Uchiyama, M., Satoh, K., Xu, J., Boyer, C., Kamigaito, M., & Qiao, G. G. (2016) · Advanced Science · doi:10.1002/advs.201500394 · Cited by 283
Self-citationYeow, J., Xu, J., & Boyer, C. (2015) · ACS Macro Letters · doi:10.1021/acsmacrolett.5b00523 · Cited by 266
Self-citationWu, C., Corrigan, N., Lim, C.-H., Liu, W., Miyake, G., & Boyer, C. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00409 · Cited by 259
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Metadata
- Authors
- Xu, J., Jung, K., Corrigan, N. A., & Boyer, C.
- Venue
- Chemical Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2014-06-30
- Volume
- 5
- Issue
- 9
- Pages
- 3568
- ISSN
- 2041-6520 (ISSN-L)
- 2041-6539
- OpenAlex
- W2083930966
- Cited by
- 216
- References
- 1
- FWCI
- 11.13
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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