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Structural enhancement of Na3V2(PO4)3/C composite cathode materials by pillar ion doping for high power and long cycle life sodium-ion batteries

Lim, Sung-Jin, Han, Dong-Wook, Nam, Do-Hwan, Hong, Kyung-Sik, Eom, Ji-Yong, Ryu, Won-Hee, Kwon, Hyuk-Sang·2014·J. Mater. Chem. A

Abstract

Structurally stabilized Na3V2(PO4)3/C composite cathode materials with excellent electrochemical performance can be obtained by incorporating functional pillar ions into the structure. As pillar ions, K-ions have a larger ionic radius compared to Na-ions, and play an important role in enlarging the Na-ion diffusion pathway and in increasing the lattice volume by elongating the c-axis, thereby improving the rate performance. Furthermore, since the incorporated K-ions rarely participate in the electrochemical extraction/insertion reactions, they can stabilize the Na3V2(PO4)3 structure by suppressing significant lattice volume changes or structural distortion, even in a wide range of voltage windows accompanying multiple transitions of V ions and phase distortions. We investigated how the K-ion doping level affected the crystal structure and electrochemical properties of Na3V2(PO4)3 cathode materials for Na-ion batteries.

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Metadata

Authors
Lim, S.-J., Han, D.-W., Nam, D.-H., Hong, K.-S., Eom, J.-Y., Ryu, W.-H., & Kwon, H.-S.
Venue
J. Mater. Chem. A
Published
2014-09-08
Volume
2
Issue
46
Pages
19623-19632
ISSN
  • 2050-7488 (ISSN-L)
  • 2050-7496
OpenAlex
W2131601462
Cited by
192
References
2
FWCI
7.08
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Structural enhancement of Na3V2(PO4)3/C composite cathode materials by pillar ion doping for high power and long cycle life sodium-ion batteries. https://app.cochat.ai/papers/10.1039/c4ta03948c
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Lim, S.-J., Han, D.-W., Nam, D.-H., Hong, K.-S., Eom, J.-Y., Ryu, W.-H., & Kwon, H.-S. (2014). Structural enhancement of Na3V2(PO4)3/C composite cathode materials by pillar ion doping for high power and long cycle life sodium-ion batteries. J. Mater. Chem. A. https://doi.org/10.1039/c4ta03948c

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