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Aggregate-based sub-CMC solubilization of n-alkanes by monorhamnolipid biosurfactant
Abstract
Monorhamnolipid biosurfactant at concentrations lower than the CMC enhances solubilization of n -alkanes due to an aggregate formation mechanism. The sub-CMC aggregate size decreases with increasing surface excess of monorhamnolipid.
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In other studies, solubilization was also observed when surfactant concentrations were below the CMC.
“Conversely, in other studies solubilization was also observed when surfactant concentrations were below the CMC (e.g., refs 50–54).”
From Contribution of Nonaqueous-Phase Liquids to the Retention and Transport of Per and Polyfluoroalkyl Substances (PFAS) in Porous Media (2021) · cites this paper as [54]
Many studies have observed increased NAPL solubilization in the presence of surfactants.
“Many studies have observed increased NAPL solubilization in the presence of surfactants.”
From Contribution of Nonaqueous-Phase Liquids to the Retention and Transport of Per and Polyfluoroalkyl Substances (PFAS) in Porous Media (2021) · cites this paper as [54]
Two proposed mechanisms for solubilization observed below the surfactant CMC are the reduction in NAPL-water interfacial tension and the formation of pre-micellar aggregates.
“Two proposed mechanisms for solubilization observed below the surfactant CMC are the reduction in NAPL-water interfacial tension and the formation of pre-micellar aggregates (e.g., refs 51–54).”
From Contribution of Nonaqueous-Phase Liquids to the Retention and Transport of Per and Polyfluoroalkyl Substances (PFAS) in Porous Media (2021) · cites this paper as [54]
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Cited by
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Van Glubt, S., & Brusseau, M. L. (2021) · Environmental Science & Technology · doi:10.1021/acs.est.0c07355 · Cited by 55
Self-citation
Metadata
- Authors
- Zhong, H., Yang, X., Tan, F., Brusseau, M. L., Yang, L., Liu, Z., Zeng, G., & Yuan, X.
- Venue
- New Journal of Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2016
- Volume
- 40
- Issue
- 3
- Pages
- 2028-2035
- ISSN
- 1144-0546
- 1369-9261
- PMC
- PMC4988678
- Cited by
- 43
- References
- 0
- Language
- en
- Funders
- National Institute of Environmental Health Sciences (P42 ES04940)
- National Natural Science Foundation of China (21276269, 51308200, 51378190, 51378192)
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