Traceless switch organocatalysis enables multiblock ring-opening copolymerizations of lactones, carbonates, and lactides: by a one plus one approach in one pot

Small-Molecule H-Bond Donors in Asymmetric Catalysis

Doyle, A. G., & Jacobsen, E. N. (2007) · Chemical Reviews · doi:10.1021/cr068373r · Cited by 2,634

Organocatalytic Ring-Opening Polymerization

Kamber, N. E., Jeong, W., Waymouth, R. M., Pratt, R. C., Lohmeijer, B. G. G., & Hedrick, J. L. (2007) · Chemical Reviews · doi:10.1021/cr068415b · Cited by 1,489

Lewis Base Catalysis in Organic Synthesis

Denmark, S. E., & Beutner, G. L. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200604943 · Cited by 1,281

Asymmetric organocatalysis

Seayad, J., & List, B. (2005) · Organic & Biomolecular Chemistry · doi:10.1039/b415217b · Cited by 1,134

Organocatalysis: Opportunities and Challenges for Polymer Synthesis

Kiesewetter, M. K., Shin, E. J., Hedrick, J. L., & Waymouth, R. M. (2010) · Macromolecules · doi:10.1021/ma9025948 · Cited by 907

Guanidine and Amidine Organocatalysts for Ring-Opening Polymerization of Cyclic Esters

Lohmeijer, B. G. G., Pratt, R. C., Leibfarth, F., Logan, J. W., Long, D. A., Dove, A. P., Nederberg, F., Choi, J., Wade, C., Waymouth, R. M., et al. (2006) · Macromolecules · doi:10.1021/ma0619381 · Cited by 816

Completely recyclable biopolymers with linear and cyclic topologies via ring-opening polymerization of γ-butyrolactone

Hong, M., & Chen, E. Y.-X. (2016) · Nature Chemistry · doi:10.1038/nchem.2391 · Cited by 677

Ring-opening copolymerization (ROCOP): synthesis and properties of polyesters and polycarbonates

Paul, S., Zhu, Y., Romain, C., Brooks, R., Saini, P. K., & Williams, C. K. (2015) · Chemical Communications · doi:10.1039/c4cc10113h · Cited by 593

Recent advances in the synthesis of aliphatic polyesters by ring-opening polymerization☆

JEROME, C., & LECOMTE, P. (2008) · Advanced Drug Delivery Reviews · doi:10.1016/j.addr.2008.02.008 · Cited by 590

Organic Catalysis for Ring-Opening Polymerization

Dove, A. P. (2012) · ACS Macro Letters · doi:10.1021/mz3005956 · Cited by 560

Triazabicyclodecene: A Simple Bifunctional Organocatalyst for Acyl Transfer and Ring-Opening Polymerization of Cyclic Esters

Pratt, R. C., Lohmeijer, B. G. G., Long, D. A., Waymouth, R. M., & Hedrick, J. L. (2006) · Journal of the American Chemical Society · doi:10.1021/ja060662+ · Cited by 543

N-Heterocyclic carbenes (NHCs) as organocatalysts and structural components in metal-free polymer synthesis

Fèvre, M., Pinaud, J., Gnanou, Y., Vignolle, J., & Taton, D. (2013) · Chemical Society Reviews · doi:10.1039/c2cs35383k · Cited by 532

First Example of N-Heterocyclic Carbenes as Catalysts for Living Polymerization: Organocatalytic Ring-Opening Polymerization of Cyclic Esters

Connor, E. F., Nyce, G. W., Myers, M., Möck, A., & Hedrick, J. L. (2002) · Journal of the American Chemical Society · doi:10.1021/ja0173324 · Cited by 472

Highly Enantioselective Direct Conjugate Addition of Ketones to Nitroalkenes Promoted by A Chiral Primary Amine−Thiourea Catalyst

Huang, H., & Jacobsen, E. N. (2006) · Journal of the American Chemical Society · doi:10.1021/ja0620890 · Cited by 446

Thiourea-Based Bifunctional Organocatalysis: Supramolecular Recognition for Living Polymerization

Dove, A. P., Pratt, R. C., Lohmeijer, B. G. G., Waymouth, R. M., & Hedrick, J. L. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0543346 · Cited by 439

Exploration, Optimization, and Application of Supramolecular Thiourea−Amine Catalysts for the Synthesis of Lactide (Co)polymers

Pratt, R. C., Lohmeijer, B. G. G., Long, D. A., Lundberg, P. N. P., Dove, A. P., Li, H., Wade, C. G., Waymouth, R. M., & Hedrick, J. L. (2006) · Macromolecules · doi:10.1021/ma061607o · Cited by 419

A Chiral Primary Amine Thiourea Catalyst for the Highly Enantioselective Direct Conjugate Addition of α,α‐Disubstituted Aldehydes to Nitroalkenes

Lalonde, M. P., Chen, Y., & Jacobsen, E. N. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200602221 · Cited by 374

Diphenyl Phosphate as an Efficient Cationic Organocatalyst for Controlled/Living Ring-Opening Polymerization of δ-Valerolactone and ε-Caprolactone

Makiguchi, K., Satoh, T., & Kakuchi, T. (2011) · Macromolecules · doi:10.1021/ma200043x · Cited by 338

Switchable Polymerization Catalysts

Teator, A. J., Lastovickova, D. N., & Bielawski, C. W. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00426 · Cited by 338

Expanding the Catalytic Activity of Nucleophilic N-Heterocyclic Carbenes for Transesterification Reactions

Nyce, G. W., Lamboy, J. A., Connor, E. F., Waymouth, R. M., & Hedrick, J. L. (2002) · Organic Letters · doi:10.1021/ol0267228 · Cited by 333

In Situ Generation of Carbenes: A General and Versatile Platform for Organocatalytic Living Polymerization

Nyce, G. W., Glauser, T., Connor, E. F., Möck, A., Waymouth, R. M., & Hedrick, J. L. (2003) · Journal of the American Chemical Society · doi:10.1021/ja021084+ · Cited by 301

Hydrogen-bonding organocatalysts for ring-opening polymerization

Thomas, C., & Bibal, B. (2013) · Green Chemistry · doi:10.1039/c3gc41806e · Cited by 290

Towards Truly Sustainable Polymers: A Metal‐Free Recyclable Polyester from Biorenewable Non‐Strained γ‐Butyrolactone

Hong, M., & Chen, E. Y. ‐. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201601092 · Cited by 259

Beyond Stereoselectivity, Switchable Catalysis: Some of the Last Frontier Challenges in Ring‐Opening Polymerization of Cyclic Esters

Guillaume, S. M., Kirillov, E., Sarazin, Y., & Carpentier, J. (2015) · Chemistry – A European Journal · doi:10.1002/chem.201500613 · Cited by 251

Cyclic Guanidine Organic Catalysts: What Is Magic About Triazabicyclodecene?

Kiesewetter, M. K., Scholten, M. D., Kirn, N., Weber, R. L., Hedrick, J. L., & Waymouth, R. M. (2009) · The Journal of Organic Chemistry · doi:10.1021/jo902369g · Cited by 227

A Simple and Efficient Synthesis of Functionalized Cyclic Carbonate Monomers Using a Versatile Pentafluorophenyl Ester Intermediate

Sanders, D. P., Fukushima, K., Coady, D. J., Nelson, A., Fujiwara, M., Yasumoto, M., & Hedrick, J. L. (2010) · Journal of the American Chemical Society · doi:10.1021/ja105332k · Cited by 219

Substituent Effect on the Anionic Equilibrium Polymerization of Six-Membered Cyclic Carbonates

Matsuo, J., Aoki, K., Sanda, F., & Endo, T. (1998) · Macromolecules · doi:10.1021/ma971227q · Cited by 188

Selective Polymerization Catalysis: Controlling the Metal Chain End Group to Prepare Block Copolyesters

Zhu, Y., Romain, C., & Williams, C. K. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b04541 · Cited by 180

Diphenyl Phosphate as an Efficient Acidic Organocatalyst for Controlled/Living Ring-Opening Polymerization of Trimethylene Carbonates Leading to Block, End-Functionalized, and Macrocyclic Polycarbonates

Makiguchi, K., Ogasawara, Y., Kikuchi, S., Satoh, T., & Kakuchi, T. (2013) · Macromolecules · doi:10.1021/ma4000495 · Cited by 165

Organo-Catalyzed ROP of ϵ-Caprolactone: Methanesulfonic Acid Competes with Trifluoromethanesulfonic Acid

Gazeau-Bureau, S., Delcroix, D., Martín-Vaca, B., Bourissou, D., Navarro, C., & Magnet, S. (2008) · Macromolecules · doi:10.1021/ma800626q · Cited by 165

Latent, Thermally Activated Organic Catalysts for the On‐Demand Living Polymerization of Lactide

Coulembier, O., Dove, A. P., Pratt, R. C., Sentman, A. C., Culkin, D. A., Mespouille, L., Dúbois, P., Waymouth, R. M., & Hedrick, J. L. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200500723 · Cited by 155

Dual Catalysis for Selective Ring-Opening Polymerization of Lactones: Evolution toward Simplicity

Naumann, S., Scholten, P. B. V., Wilson, J. A., & Dove, A. P. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b09502 · Cited by 143

Organocatalysis Paradigm Revisited: Are Metal-Free Catalysts Really Harmless?

Nachtergael, A., Coulembier, O., Dúbois, P., Helvenstein, M., Duez, P., Blankert, B., & Mespouille, L. (2014) · Biomacromolecules · doi:10.1021/bm5015443 · Cited by 143

Ring-Opening Polymerization of Trimethylene Carbonate Catalyzed by Methanesulfonic Acid: Activated Monomer versus Active Chain End Mechanisms

Delcroix, D., Martín-Vaca, B. M., Bourissou, D., & Navarro, C. (2010) · Macromolecules · doi:10.1021/ma101461y · Cited by 140

Conjugate‐Addition Organopolymerization: Rapid Production of Acrylic Bioplastics by N‐Heterocyclic Carbenes

Zhang, Y., & Chen, E. Y. ‐. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201108019 · Cited by 138

Sequence Selective Polymerization Catalysis: A New Route to ABA Block Copoly(ester- b -carbonate- b -ester)

Paul, S., Romain, C., Shaw, J. S., & Williams, C. K. (2015) · Macromolecules · doi:10.1021/acs.macromol.5b01293 · Cited by 137

Photoswitchable NHC-promoted ring-opening polymerizations

Neilson, B. M., & Bielawski, C. W. (2013) · Chemical Communications · doi:10.1039/c3cc42424c · Cited by 134

Catalytic insights into acid/base conjugates: highly selective bifunctional catalysts for the ring-opening polymerization of lactide

Coady, D. J., Fukushima, K., Horn, H. W., Rice, J. E., & Hedrick, J. L. (2011) · Chemical Communications · doi:10.1039/c0cc03987j · Cited by 133

Highly Polarized Alkenes as Organocatalysts for the Polymerization of Lactones and Trimethylene Carbonate

Naumann, S., Thomas, A. W., & Dove, A. P. (2016) · ACS Macro Letters · doi:10.1021/acsmacrolett.5b00873 · Cited by 97

Clicking Well‐Defined Biodegradable Nanoparticles and Nanocapsules by UV‐Induced Thiol‐Ene Cross‐Linking in Transparent Miniemulsions

Zou, J., Hew, C. C., Themistou, E., Li, Y., Chen, C., Alexandridis, P., & Cheng, C. (2011) · Advanced Materials · doi:10.1002/adma.201101646 · Cited by 97

Cooperative Hydrogen-Bond Pairing in Organocatalytic Ring-Opening Polymerization

Kazakov, O. I., Datta, P. P., Isajani, M., Kiesewetter, E. T., & Kiesewetter, M. K. (2014) · Macromolecules · doi:10.1021/ma501847x · Cited by 85

Ring-Opening Polymerization of l -Lactide Catalyzed by an Organocatalytic System Combining Acidic and Basic Sites

Kadota, J., Pavlović, D., Desvergne, J., Bibal, B., Peruch, F., & Deffieux, A. (2010) · Macromolecules · doi:10.1021/ma101688d · Cited by 85

Neutral and Cationic N‐Heterocyclic Carbene Zinc Adducts and the BnOH/Zn(C6F5)2 Binary Mixture – Characterization and Use in the Ring‐Opening Polymerization of β‐Butyrolactone, Lactide, and Trimethylene Carbonate

Schnee, G., Fliedel, C., Avilés, T., & Dagorne, S. (2013) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.201300292 · Cited by 80

Hydrophilic Polycarbonates: Promising Degradable Alternatives to Poly(ethylene glycol)-Based Stealth Materials

Engler, A. C., Ke, X., Gao, S., Chan, J. M. W., Coady, D. J., Ono, R. J., Lubbers, R., Nelson, A., Yang, Y. Y., & Hedrick, J. L. (2015) · Macromolecules · doi:10.1021/acs.macromol.5b00156 · Cited by 77

Macromolecular engineering viaring-opening polymerization (1): l -lactide/trimethylene carbonate block copolymers as thermoplastic elastomers

Guerin, W., Helou, M., Carpentier, J.-F., Slawinski, M., Brusson, J.-M., & Guillaume, S. M. (2013) · Polym. Chem. · doi:10.1039/c2py20859h · Cited by 75

High activity of an indium alkoxide complex toward ring opening polymerization of cyclic esters

Quan, S. M., & Diaconescu, P. L. (2015) · Chemical Communications · doi:10.1039/c5cc01312g · Cited by 69

Rate Accelerated Organocatalytic Ring-Opening Polymerization of l-Lactide via the Application of a Bis(thiourea) H-bond Donating Cocatalyst

Spink, S. S., Kazakov, O. I., Kiesewetter, E. T., & Kiesewetter, M. K. (2015) · Macromolecules · doi:10.1021/acs.macromol.5b01320 · Cited by 68

Diphenyl phosphate/4-dimethylaminopyridine as an efficient binary organocatalyst system for controlled/living ring-opening polymerization of L-lactide leading to diblock and end-functionalized poly(L-lactide)s

Makiguchi, K., Kikuchi, S., Yanai, K., Ogasawara, Y., Sato, S.-I., Satoh, T., & Kakuchi, T. (2014) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.27089 · Cited by 67

Ring-opening polymerization of lactones using supramolecular organocatalysts under simple conditions

Thomas, C., Peruch, F., & Bibal, B. (2012) · RSC Advances · doi:10.1039/c2ra22535b · Cited by 67

P,O-Phosphinophenolate zinc( ii ) species: synthesis, structure and use in the ring-opening polymerization (ROP) of lactide, ε-caprolactone and trimethylene carbonate

Fliedel, C., Rosa, V., Alves, F. M., Martins, A. M., Avilés, T., & Dagorne, S. (2015) · Dalton Transactions · doi:10.1039/c5dt00458f · Cited by 65

Mild and Efficient Preparation of Block and Gradient Copolymers by Methanesulfonic Acid Catalyzed Ring-Opening Polymerization of Caprolactone and Trimethylene Carbonate

Couffin, A., Delcroix, D., Martín-Vaca, B. M., Bourissou, D., & Navarro, C. (2013) · Macromolecules · doi:10.1021/ma400916k · Cited by 65

Facile Synthesis of Functionalized Lactones and Organocatalytic Ring-Opening Polymerization

Kim, H., Olsson, J. V., Hedrick, J. L., & Waymouth, R. M. (2012) · ACS Macro Letters · doi:10.1021/mz3001397 · Cited by 63

Controlled bulk polymerization of l-lactide and lactones by dual activation with organo-catalytic systems

Kadota, J., Pavlović, D., Hirano, H., Okada, A., Agari, Y., Bibal, B., Deffieux, A., & Peruch, F. (2014) · RSC Advances · doi:10.1039/c4ra01239a · Cited by 57

A squaramide and tertiary amine: an excellent hydrogen-bonding pair organocatalyst for living polymerization

Liu, J., Chen, C., Li, Z., Wu, W., Zhi, X., Zhang, Q., Wu, H., Wang, X., Cui, S., & Guo, K. (2015) · Polymer Chemistry · doi:10.1039/c5py00508f · Cited by 54

A base–conjugate-acid pair for living/controlled ring-opening polymerization of trimethylene carbonate through hydrogen-bonding bifunctional synergistic catalysis

Wang, X., Cui, S., Li, Z., Kan, S., Zhang, Q., Zhao, C., Wu, H., Liu, J., Wu, W., & Guo, K. (2014) · Polymer Chemistry · doi:10.1039/c4py00773e · Cited by 52

Highly Efficient Aluminum-Catalyzed Ring-Opening Polymerization of Cyclic Carbonates, Lactones, and Lactides, Including a Unique Crystallographic Snapshot of an Intermediate

Koller, J., & Bergman, R. G. (2011) · Organometallics · doi:10.1021/om2003283 · Cited by 50

External and Reversible CO2 Regulation of Ring-Opening Polymerizations Based on a Primary Alcohol Propagating Species

Coulembier, O., Moins, S., Todd, R., & Dúbois, P. (2014) · Macromolecules · doi:10.1021/ma4024944 · Cited by 49

Macromolecular engineering via ring-opening polymerization (2): l-lactide/trimethylene carbonate copolymerization – kinetic and microstructural control via catalytic tuning

Guerin, W., Hélou, M., Slawinski, M., Brusson, J., Guillaume, S. M., & Carpentier, J. (2013) · Polymer Chemistry · doi:10.1039/c3py00397c · Cited by 48

An imidazole-based organocatalyst designed for bulk polymerization of lactide isomers: inspiration from Nature

Coulembier, O., Josse, T., Guillerm, B., Gerbaux, P., & Dúbois, P. (2012) · Chemical Communications · doi:10.1039/c2cc37061a · Cited by 48

Selective O -acyl ring-opening of β-butyrolactone catalyzed by trifluoromethane sulfonic acid: application to the preparation of well-defined block copolymers

Couffin, A., Martín-Vaca, B., Bourissou, D., & Navarro, C. (2014) · Polymer Chemistry · doi:10.1039/c3py00935a · Cited by 44

Ionic hydrogen bond donor organocatalyst for fast living ring-opening polymerization

Zhi, X., Liu, J., Li, Z., Wang, H., Wang, X., Cui, S., Chen, C., Zhao, C., Li, X., & Guo, K. (2015) · Polymer Chemistry · doi:10.1039/c5py01315a · Cited by 42

Block and Random Copolymers of 1,2-Cyclohexyl Cyclocarbonate and l -Lactide or Trimethylene Carbonate Synthesized by Ring-Opening Polymerization

Diallo, A. K., Guerin, W., Slawinski, M., Brusson, J., Carpentier, J., & Guillaume, S. M. (2015) · Macromolecules · doi:10.1021/acs.macromol.5b00548 · Cited by 41

Lactide, β-butyrolactone, δ-valerolactone, and ε-caprolactone polymerization with copper diketiminate complexes

Whitehorne, T. J. J., & Schaper, F. (2013) · Canadian Journal of Chemistry · doi:10.1139/cjc-2013-0392 · Cited by 35

Tripodal hydrogen bond donor binding with sulfonic acid enables ring-opening polymerization

Li, X., Zhang, Q., Li, Z., Xu, S., Zhao, C., Chen, C., Zhi, X., Wang, H., Zhu, N., & Guo, K. (2016) · Polymer Chemistry · doi:10.1039/c5py01931a · Cited by 32

Living and immortal polymerization of seven and six membered lactones to high molecular weights with aluminum salen and salan catalysts

MacDonald, J. P., Sidera, M., Fletcher, S. P., & Shaver, M. P. (2015) · European Polymer Journal · doi:10.1016/j.eurpolymj.2015.11.032 · Cited by 27

Poly(trimethylene carbonate)/Poly(malic acid) Amphiphilic Diblock Copolymers as Biocompatible Nanoparticles

Barouti, G., Khalil, A., Orione, C., Jarnouen, K., Cammas‐Marion, S., Loyer, P., & Guillaume, S. M. (2016) · Chemistry - A European Journal · doi:10.1002/chem.201504824 · Cited by 24

Three is company: dual intramolecular hydrogen-bond enabled carboxylic acid active in ring-opening polymerization

Xu, J., Liu, J., Li, Z., Li, X., Chen, C., Zhao, C., Xu, S., Pan, X., Liu, J., & Guo, K. (2015) · Polymer Chemistry · doi:10.1039/c5py01635e · Cited by 23

Molecular Structure–Catalytic Activity Relationship in the Ring-Opening Polymerization of (Macro)lactones

Pepels, M. P. F., Hermsen, I., Noordzij, G. J., & Duchateau, R. (2016) · Macromolecules · doi:10.1021/acs.macromol.5b02391 · Cited by 23

Macromolecular engineering via ring-opening polymerization (3): trimethylene carbonate block copolymers derived from glycerol

Guerin, W., Hélou, M., Slawinski, M., Brusson, J., Carpentier, J., & Guillaume, S. M. (2013) · Polymer Chemistry · doi:10.1039/c3py00955f · Cited by 22

Thiourea binding with carboxylic acid promoted cationic ring-opening polymerization

Li, X., Zhang, Q., Li, Z., Wang, X., Liu, J., Cui, S., Xu, S., Zhao, C., Chen, C., & Guo, K. (2016) · Polymer · doi:10.1016/j.polymer.2015.12.057 · Cited by 22

Zinc complexes coordinated by bipyridine-phenolate ligands as an efficient initiator for ring-opening polymerization of cyclic esters

Hsieh, Y., Lin, Y.-C., Lee, G., & Peng, C. (2014) · Polymer · doi:10.1016/j.polymer.2014.12.001 · Cited by 17

New Paradigms for Organic Catalysts: The First Organocatalytic Living Polymerization

Nederberg, F., Connor, E. F., Möller, M., Glauser, T., & Hedrick, J. L. (2001) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20010716)40:14<2712::aid-anie2712>3.0.co;2-z

Strategies for the synthesis of block copolymers with biodegradable polyester segments

Diaz, C., & Mehrkhodavandi, P. (2021) · Polymer Chemistry · doi:10.1039/d0py01534b · Cited by 74

A simple and general approach for the synthesis of biodegradable triblock copolymers by organocatalytic ROP from poly(lactide) macroinitiators

Toshikj, N., Robin, J.-J., & Blanquer, S. (2020) · European Polymer Journal · doi:10.1016/j.eurpolymj.2020.109599 · Cited by 24