The DOI matches its Crossref record; 13 of the 13 references it cites were found in a registry or an index.
Potential energy surface crossings in organic photochemistry
Abstract
Modern experiments and quantum chemical computations show that low lying potential energy surface crossings (conical and singlet-triplet intersections) are a general feature of photochemically relevant excited states. This review focuses on the computational and experimental investigation of the efficiency of internal conversion at a surface crossing, the competition with fluorescence when an excited state barrier is present, and the relationship between the molecular structure at the intersection and structure of the photoproducts. It is shown that single or successive low-lying intersections provide the bottlenecks controlling the evolution of a photoexcited molecule from the Franck-Condon region to the photoproduct valleys.
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Citations
Cites
Multimode molecular dynamics beyond the Born-Oppenheimer approximation
Köppel, H., Domcke, W., & Cederbaum, L. S. (1984) · Advances in chemical physics · Cited by 995
A direct method for the location of the lowest energy point on a potential surface crossing
Bearpark, M. J., Robb, M. A., & Bernhard Schlegel, H. (1994) · Chemical Physics Letters · doi:10.1016/0009-2614(94)00433-1 · Cited by 673
Self-citationVibrationally Coherent Photochemistry in the Femtosecond Primary Event of Vision
Wang, Q., Schoenlein, R. W., Peteanu, L. A., Mathies, R. A., & Shank, C. V. (1994) · Science · doi:10.1126/science.7939680 · Cited by 636
An MC-SCF study of the S1 and S2 photochemical reactions of benzene
Palmer, I. J., Ragazos, I. N., Bernardi, F., Olivucci, M., & Robb, M. A. (1993) · Journal of the American Chemical Society · doi:10.1021/ja00055a042 · Cited by 260
Self-citationSymmetry control and photoinduced reactions
Van der Lugt, W. T. A. M., & Oosterhoff, L. J. (1969) · Journal of the American Chemical Society · doi:10.1021/ja01050a019 · Cited by 248
Ragazos, I. N., Robb, M. A., Bernardi, F., & Olivucci, M. (1992) · Chemical Physics Letters · doi:10.1016/0009-2614(92)85758-3 · Cited by 185
Self-citationThe Azulene S1 State Decays via a Conical Intersection: A CASSCF Study with MMVB Dynamics
Bearpark, M. J., Bernardi, F., Clifford, S., Olivucci, M., Robb, M. A., Smith, B. R., & Vreven, T. (1996) · Journal of the American Chemical Society · doi:10.1021/ja9514555 · Cited by 177
Self-citationZimmerman, H. E. (1966) · Journal of the American Chemical Society · doi:10.1021/ja00959a053 · Cited by 160
Cyr, D. R., & Hayden, C. C. (1996) · The Journal of Chemical Physics · doi:10.1063/1.470802 · Cited by 135
Smith, B. R., Bearpark, M. J., Robb, M. A., Bernardi, F., & Olivucci, M. (1995) · Chemical Physics Letters · doi:10.1016/0009-2614(95)00718-j · Cited by 107
Self-citation
Cited by
Grabowski, Z. R., Rotkiewicz, K., & Rettig, W. (2003) · Chemical Reviews · doi:10.1021/cr940745l · Cited by 3,714
Levine, R. D. (2005) · Cambridge University Press eBooks · doi:10.1017/cbo9780511614125 · Cited by 709
Improta, R., Santoro, F., & Blancafort, L. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00444 · Cited by 499
Mechanisms associated with biogenesis of exosomes in cancer
McAndrews, K. M., & Kalluri, R. (2019) · Molecular Cancer · doi:10.1186/s12943-019-0963-9 · Cited by 394
Nonadiabatic Events and Conical Intersections
Matsika, S., & Krause, P. (2011) · Annual Review of Physical Chemistry · doi:10.1146/annurev-physchem-032210-103450 · Cited by 309
Metadata
- Authors
- Bernardi, F., Olivucci, M., & Robb, M. A.
- Venue
- Chemical Society Reviews
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 1996
- Volume
- 25
- Issue
- 5
- Pages
- 321
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W1982368957
- Cited by
- 818
- References
- 13
- FWCI
- 6.91
- Type
- journal article
- Language
- en
- Open access
- closed
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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