Analysis of Pyrethroids in Cereals by HPLC with a Deep Eutectic Solvent-Based Dispersive Liquid–Liquid Microextraction with Solidification of Floating Organic Droplets

Deep Eutectic Solvents (DESs) and Their Applications

Smith, E. L., Abbott, A. P., & Ryder, K. S. (2014) · Chemical Reviews · doi:10.1021/cr300162p · Cited by 7,378 · see citing works

Deep eutectic solvents: syntheses, properties and applications

Zhang, Q., De Oliveira Vigier, K., Royer, S., & Jérôme, F. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35178a · Cited by 4,899 · see citing works

Hydrophobic deep eutectic solvents as water-immiscible extractants

van Osch, D. J. G. P., Zubeir, L. F., van den Bruinhorst, A., Rocha, M. A. A., & Kroon, M. C. (2015) · Green Chemistry · doi:10.1039/c5gc01451d · Cited by 987 · see citing works

Hydrophobic deep eutectic solvents in microextraction techniques–A review

Makoś, P., Słupek, E., & Gębicki, J. (2020) · Microchemical Journal · doi:10.1016/j.microc.2019.104384 · Cited by 469 · see citing works

Densities of ammonium and phosphonium based deep eutectic solvents: Prediction using artificial intelligence and group contribution techniques

Shahbaz, K., Baroutian, S., Mjalli, F. S., Hashim, M. A., & AlNashef, I. M. (2011) · Thermochimica Acta · doi:10.1016/j.tca.2011.10.010 · Cited by 367 · see citing works

Hexafluoroisopropanol-based hydrophobic deep eutectic solvents for dispersive liquid-liquid microextraction of pyrethroids in tea beverages and fruit juices

Deng, W., Yu, L., Li, X., Chen, J., Wang, X., Deng, Z., & Xiao, Y. (2019) · Food Chemistry · doi:10.1016/j.foodchem.2018.09.048 · Cited by 168 · see citing works

Deep eutectic solvent-based dispersive liquid-liquid micro-extraction of pesticides in food samples

Musarurwa, H., & Tavengwa, N. T. (2021) · Food Chemistry · doi:10.1016/j.foodchem.2020.127943 · Cited by 159 · see citing works

Design and evaluation of polarity controlled and recyclable deep eutectic solvent based biphasic system for the polarity driven extraction and separation of compounds

Tang, W., & Row, K. H. (2020) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2020.122306 · Cited by 138 · see citing works

Low-density solvent-based vortex-assisted surfactant-enhanced-emulsification liquid–liquid microextraction combined with gas chromatography–mass spectrometry for the fast determination of phthalate esters in bottled water

Zhang, Y., & Lee, H. K. (2012) · Journal of Chromatography A · doi:10.1016/j.chroma.2012.12.017 · Cited by 136 · see citing works

A highly selective and sensitive ultrasonic assisted dispersive liquid phase microextraction based on deep eutectic solvent for determination of cadmium in food and water samples prior to electrothermal atomic absorption spectrometry

Zounr, R. A., Tuzen, M., Deligonul, N., & Khuhawar, M. Y. (2018) · Food Chemistry · doi:10.1016/j.foodchem.2018.01.167 · Cited by 127 · see citing works

In-syringe dispersive liquid-liquid microextraction using deep eutectic solvent as disperser: Determination of chromium (VI) in beverages

Shishov, A., Terno, P., Moskvin, L., & Bulatov, A. (2020) · Talanta · doi:10.1016/j.talanta.2019.120209 · Cited by 107 · see citing works

Evaluation of CO2-induced azole-based switchable ionic liquid with hydrophobic/hydrophilic reversible transition as single solvent system for coupling lipid extraction and separation from wet microalgae

Tang, W., & Row, K. H. (2019) · Bioresource Technology · doi:10.1016/j.biortech.2019.122309 · Cited by 104 · see citing works

Separation/preconcentration and determination of vanadium with dispersive liquid–liquid microextraction based on solidification of floating organic drop (DLLME-SFO) and electrothermal atomic absorption spectrometry

Asadollahi, T., Dadfarnia, S., & Shabani, A. M. H. (2010) · Talanta · doi:10.1016/j.talanta.2010.04.020 · Cited by 103 · see citing works

Speciation of As(III) and As(V) in water samples by graphite furnace atomic absorption spectrometry after solid phase extraction combined with dispersive liquid–liquid microextraction based on the solidification of floating organic drop

Shamsipur, M., Fattahi, N., Assadi, Y., Sadeghi, M., & Sharafi, K. (2014) · Talanta · doi:10.1016/j.talanta.2014.06.049 · Cited by 100 · see citing works

Exposure to pyrethroid pesticides and the risk of childhood brain tumors in East China

Chen, S., Gu, S., Wang, Y., Yao, Y., Wang, G., Jin, Y., & Wu, Y. (2016) · Environmental Pollution · doi:10.1016/j.envpol.2016.08.066 · Cited by 97 · see citing works

Technologies for enhancement of bioactive components and potential health benefits of cereal and cereal-based foods: Research advances and application challenges

Saleh, A. S. M., Wang, P., Wang, N., Yang, S., & Xiao, Z. (2017) · Critical Reviews in Food Science and Nutrition · doi:10.1080/10408398.2017.1363711 · Cited by 95 · see citing works

Determination of pyrethroid pesticide residues in vegetables by pressurized capillary electrochromatography

Ye, F., Xie, Z., Wu, X., & Lin, X. (2005) · Talanta · doi:10.1016/j.talanta.2005.09.006 · Cited by 94 · see citing works

Combination of microwave-assisted extraction and ultrasonic-assisted dispersive liquid-liquid microextraction for separation and enrichment of pyrethroids residues in Litchi fruit prior to HPLC determination

Wang, K., Xie, X., Zhang, Y., Huang, Y., Zhou, S., Zhang, W., Lin, Y., & Fan, H. (2017) · Food Chemistry · doi:10.1016/j.foodchem.2017.08.061 · Cited by 83 · see citing works

Dispersive liquid–liquid microextraction based on hydrophobic deep eutectic solvents: Application for tetracyclines monitoring in milk

Sereshti, H., Jazani, S. S., Nouri, N., & Shams, G. (2020) · Microchemical Journal · doi:10.1016/j.microc.2020.105269 · Cited by 82 · see citing works

Simultaneous derivatization and air–assisted liquid–liquid microextraction based on solidification of lighter than water deep eutectic solvent followed by gas chromatography–mass spectrometry: An efficient and rapid method for trace analysis of aromatic amines in aqueous samples

Torbati, M., Mohebbi, A., Farajzadeh, M. A., & Mogaddam, M. R. A. (2018) · Analytica Chimica Acta · doi:10.1016/j.aca.2018.06.025 · Cited by 79 · see citing works

Ultrasound-assisted dispersive liquid–liquid microextraction based on the solidification of a floating organic droplet followed by gas chromatography for the determination of eight pyrethroid pesticides in tea samples

Hou, X., Zheng, X., Zhang, C., Ma, X., Ling, Q., & Zhao, L. (2014) · Journal of Chromatography B · doi:10.1016/j.jchromb.2014.08.010 · Cited by 75 · see citing works

Pyrethroids in indoor air during application of various mosquito repellents: Occurrence, dissipation and potential exposure risk

Li, H., Lydy, M. J., & You, J. (2015) · Chemosphere · doi:10.1016/j.chemosphere.2015.11.025 · Cited by 56 · see citing works

Recoverable deep eutectic solvent-based aniline organic pollutant separation technology using choline salt as adsorbent

Tang, W., An, Y., & Row, K. H. (2020) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2020.112910 · Cited by 50 · see citing works

Dispersive liquid–liquid microextraction coupled with programmed temperature vaporization-large volume injection-gas chromatography–tandem mass spectrometry for multiclass pesticides in water

Carro, A. M., Fernández, S., Racamonde, I., García-Rodríguez, D., González, P., & Lorenzo, R. A. (2012) · Journal of Chromatography A · doi:10.1016/j.chroma.2012.06.089 · Cited by 45 · see citing works

Analysis of phenolic pollutants in human samples by high performance capillary electrophoresis based on pretreatment of ultrasound-assisted emulsification microextraction and solidification of floating organic droplet

Wang, H., Yan, H., Wang, C., Chen, F., Ma, M., Wang, W., & Wang, X. (2012) · Journal of Chromatography A · doi:10.1016/j.chroma.2012.06.088 · Cited by 40 · see citing works

MultiSimplex optimization of the dispersive solid-phase microextraction and determination of fenitrothion by magnetic molecularly imprinted polymer and high-performance liquid chromatography

Bazmandegan‐Shamili, A., Dadfarnia, S., Shabani, A. M. H., Moghadam, M. R., & Saeidi, M. (2018) · Journal of the Iranian Chemical Society · doi:10.1007/s13738-018-1316-0 · Cited by 37 · see citing works

Microbial transformation of chiral organohalides: Distribution, microorganisms and mechanisms

Lu, Q., Qiu, L., Yu, L., Zhang, S., de Toledo, R. A., Shim, H., & Wang, S. (2019) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2019.01.103 · Cited by 35 · see citing works

Determination of Pyrethroid Insecticides in Vegetables with Liquid Chromatography Using Detection by Electrospray Mass Spectrometry

Martínez, D. B., Vázquez, P. P., Galera, M. M., & García, M. D. G. (2006) · Chromatographia · doi:10.1365/s10337-006-0777-y · Cited by 34 · see citing works

Stereoselective Analysis of Chiral Pyrethroid Insecticides Tetramethrin and α-Cypermethrin in Fruits, Vegetables, and Cereals

Zhao, P., Dong, X., Chen, X., Guo, X., & Zhao, L. (2019) · Journal of Agricultural and Food Chemistry · doi:10.1021/acs.jafc.9b01850 · Cited by 34 · see citing works

Analysis of permethrin isomers in composite diet samples by molecularly imprinted solid-phase extraction and isotope dilution gas chromatography–ion trap mass spectrometry

Vonderheide, A. P., Boyd, B. L., Ryberg, A., Yilmaz, E., Hieber, T. E., Kauffman, P. E., Garris, S. T., & Morgan, J. N. (2009) · Journal of Chromatography A · doi:10.1016/j.chroma.2009.03.077 · Cited by 29 · see citing works

A novel procedure for phase separation in dispersive liquid-liquid microextraction based on solidification of the aqueous phase

March, J. G., & Cerdà, V. (2016) · Talanta · doi:10.1016/j.talanta.2016.05.027 · Cited by 21 · see citing works

Determination of Pyrethroid Pesticides in Tomato Using Ionic Liquid-Based Dispersive Liquid-Liquid Microextraction

Han, D., Tang, B., & Row, K. H. (2013) · Journal of Chromatographic Science · doi:10.1093/chromsci/bmt017 · Cited by 17 · see citing works

Vortex‐assisted Emulsification Microextraction for the Determination of Pyrethroids in Mushroom

Zhao, W., Jing, X., Chang, M., Meng, J., & Feng, C. (2019) · Bulletin of the Korean Chemical Society · doi:10.1002/bkcs.11850 · Cited by 9 · see citing works

Hydrophobic Deep Eutectic Solvents as Greener Substitutes for Conventional Extraction Media: Examples and Techniques

Devi, M., Moral, R., Thakuria, S., Mitra, A., & Paul, S. (2023) · ACS Omega · doi:10.1021/acsomega.2c07684 · Cited by 194 · see citing works

Deep eutectic solvents in sample preparation and determination methods of pesticides: Recent advances and future prospects

Hu, C., Feng, J., Cao, Y., Chen, L., & Li, Y. (2023) · Talanta · doi:10.1016/j.talanta.2023.125092 · Cited by 70 · see citing works

Dispersive Liquid–Liquid Micro Extraction: An Analytical Technique Undergoing Continuous Evolution and Development—A Review of the Last 5 Years

Notardonato, I., & Avino, P. (2024) · Separations · doi:10.3390/separations11070203 · Cited by 60 · see citing works

Deep Eutectic Solvents as Promising Green Solvents in Dispersive Liquid–Liquid Microextraction Based on Solidification of Floating Organic Droplet: Recent Applications, Challenges and Future Perspectives

El-Deen, A. K., & Shimizu, K. (2021) · Molecules · doi:10.3390/molecules26237406 · Cited by 58 · see citing works

Assessing the greenification potential of cyclodextrin-based molecularly imprinted polymers for pesticides detection

Farooq, S., Xu, L., Ostovan, A., Qin, C., Liu, Y., Pan, Y., Ping, J. F., & Ying, Y. B. (2023) · Food Chemistry · doi:10.1016/j.foodchem.2023.136822 · Cited by 52 · see citing works

Application of deep eutectic solvents in analytical sample pretreatment (update 2017–2022). Part A: Liquid phase microextraction

Andruch, V., Kalyniukova, A., Płotka‐Wasylka, J., Jatkowska, N., Snigur, D. V., Zaruba, S., Płatkiewicz, J., Zgoła‐Grześkowiak, A., & Werner, J. (2023) · Microchemical Journal · doi:10.1016/j.microc.2023.108509 · Cited by 42 · see citing works

Low-density solvent-based liquid-liquid microextraction for separation of trace concentrations of different analytes

Snigur, D. V., Azooz, E. A., Zhukovetska, O., Гузенко, Е. М., & Mortada, W. I. (2023) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2023.117260 · Cited by 42 · see citing works

Behaviour of deep eutectic solvent based on terpenoid and long-chain alcohol during dispersive liquid-liquid microextraction: Determination of zearalenone in cereal samples

Pochivalov, A., Pavlova, K., Garmonov, S. Y., & Bulatov, A. V. (2022) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2022.120231 · Cited by 39 · see citing works

Strategies of dispersive liquid-liquid microextraction for coastal zone environmental pollutant determination

Wang, Y., Li, J., Sun, D., Yang, S., Liu, H., & Chen, L. (2021) · Journal of Chromatography A · doi:10.1016/j.chroma.2021.462615 · Cited by 38 · see citing works

Sorptive extraction of pesticides from food and environmental samples using metal organic framework-based adsorbents

Musarurwa, H., Chimuka, L., & Tavengwa, N. T. (2021) · Trends in Environmental Analytical Chemistry · doi:10.1016/j.teac.2021.e00141 · Cited by 25 · see citing works

Natural Deep Eutectic Solvents as a Green Alternative for Extracting Contaminants from Food Samples: A Review

Luque‐Uría, Á., González, F. P., Navarro-Villoslada, F., & Benito‐Peña, E. (2025) · Journal of Analysis and Testing · doi:10.1007/s41664-025-00383-w · Cited by 24 · see citing works

On-site sample pretreatment: Natural deep eutectic solvent-based multiple air-assisted liquid–liquid microextraction

Yang, Y., Liu, W., Hang, N., Zhao, W., Lu, P., & Li, S. (2022) · Journal of Chromatography A · doi:10.1016/j.chroma.2022.463136 · Cited by 23 · see citing works

Deep eutectic solvents for microextraction of endocrine disruptor contaminants from water and food: Review

Cunha, S. C., Lapa, R. A. S., & Fernandes, J. O. (2023) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2023.117495 · Cited by 23 · see citing works

(Natural) deep eutectic solvents in food safety: Innovations in sample preparation

Carbonell‐Rozas, L., Capilla-Flores, R., Romero‐González, R., & Frenich, A. G. (2025) · Advances in Sample Preparation · doi:10.1016/j.sampre.2025.100188 · Cited by 21 · see citing works

New family of type V natural hydrophobic deep eutectic solvents based on thymol-acetamide/acetanilide: Characteristics, intermolecular interactions and applications in liquid–liquid extraction

Rafati, S., Ebrahimi, N., & Sadeghi, R. (2024) · Separation and Purification Technology · doi:10.1016/j.seppur.2024.130583 · Cited by 20 · see citing works

Application of deep eutectic solvents for the simultaneous determination of organophosphorus and pyrethroid pesticides in aqueous matrices and the assessment of its level of whiteness

Slominski, W. H., dos Santos, V. B., Xavier, F. R., Gariani, R. A., & Martendal, E. (2025) · Journal of Chromatography A · doi:10.1016/j.chroma.2025.465770 · Cited by 13 · see citing works

Nanoporous carbon derived ZIF-67@MWCNTs-Fe3O4 reinforced hollow fiber to performe hollow fiber solid-phase micro extraction (HF-SPME) coupled with high-performance liquid chromatography to determine deltamethrin and cypermethrin

Ahmadi, A., Alinezhad, H., Sarrafi, Y., & Ghani, M. (2024) · Journal of Food Composition and Analysis · doi:10.1016/j.jfca.2024.106750 · Cited by 12 · see citing works

Deep eutectic solvents in microextraction

Alshana, U., & Soylak, M. (2021) · Elsevier eBooks · doi:10.1016/b978-0-12-822139-6.00019-5 · Cited by 12 · see citing works

Application of Extraction and Determination Based on Deep Eutectic Solvents in Different Types of Environmental Samples

Wang, Y., Li, N., Jiang, S., & Chen, X. (2021) · Water · doi:10.3390/w14010046 · Cited by 10 · see citing works

Targeted Multiresidue Method for the Analysis of Different Classes of Pesticides in Agro-Food Industrial Sludge by Liquid Chromatography Tandem Mass Spectrometry

Maragou, N. C., Balayiannis, G., Karanasios, E., Markellou, E., & Liapis, K. S. (2021) · Molecules · doi:10.3390/molecules26226888 · Cited by 9 · see citing works

Application of natural deep eutectic solvents for the extraction of plasticizers in laying hen and goat feed

Santana‐Mayor, Á., Socas‐Rodríguez, B., Rodríguez‐Ramos, R., Herrera‐Herrera, A. V., & Rodríguez‐Delgado, M. Á. (2023) · Microchemical Journal · doi:10.1016/j.microc.2023.109072 · Cited by 9 · see citing works

A Novel DLLME Method Involving a Solidifying Hydrophobic Deep Eutectic Solvent Using Hydrophilic Deep Eutectic Solvent as the Dispersant for the Determination of Polychlorinated Biphenyls in Water Samples

Peng, C., Zhang, S., & Li, X. (2024) · Molecules · doi:10.3390/molecules29153480 · Cited by 5 · see citing works

Cyclodextrin-assisted dispersive liquid-liquid microextraction based on solidification of floating organic droplets coupled with HPLC for the determination of pyrethroid residues in cereals

Jiang, H., Bi, X., Huang, X., Guo, X., Zou, Z., Li, Y., Jing, X., & Wu, J. (2022) · Acta Chromatographica · doi:10.1556/1326.2021.00991 · Cited by 5 · see citing works

Recent trends in microextraction methodology for food analysis

Salehpour, N., Nojavan, S., Alahmad, W., & Tabani, H. (2024) · Elsevier eBooks · doi:10.1016/b978-0-443-18957-9.00010-9 · Cited by 3 · see citing works

The Neglected Dimension in Pesticide Residues: Emerging Green and Enantioselective Strategies for the Analysis and Removal of Chiral Pesticides

Liu, B., Gong, Z., & Gao, H. (2025) · Separations · doi:10.3390/separations13010004 · Cited by 2 · see citing works

Eco-Friendly Deep Eutectic Solvent-Based Extraction Technologies: A Comprehensive Review of Principles, Applications, and Comparative Insights

Alahmadi, S. M., & Abu-Dief, A. M. (2026) · Sustainable Chemistry · doi:10.3390/suschem7030033 · Cited by 1 · see citing works

Experimental-design-based optimization of dispersive liquid-liquid microextraction coupled with gas chromatography–negative-ion chemical ionization–mass spectrometry for the determination of pyrethroids in agricultural products and drinks

Wang, Y., Wang, J., & Shu, Y.-Y. (2025) · Food Additives & Contaminants Part A · doi:10.1080/19440049.2024.2447054 · Cited by 1 · see citing works

Slug Flow Liquid–Liquid Extraction of Deferiprone as Iron Complex Using Natural Deep Eutectic Solvents in a Cross-Flow T-Junction Microfluidic System

Rezaei, N., Ghanbari, S., Bijarchi, M. A., Seidi, S., & Sillanpää, M. (2025) · Langmuir · doi:10.1021/acs.langmuir.5c03415 · Cited by 1 · see citing works

Solvent-based extraction techniques for the determination of pesticides in food

Mortada, W. I., & Abdallah, A. B. (2024) · Elsevier eBooks · doi:10.1016/b978-0-443-15978-7.00058-8

Sample preparation for food contaminant analysis

Souza-Silva, É. A., & Jaccoud, A. D. (2024) · Elsevier eBooks · doi:10.1016/b978-0-443-15978-7.00108-9

High-Pressure Densities and Derived Properties of Thymol/Carboxylic Acid Eutectic Mixtures

Chen, X., Jing, W., & Wang, X. (2026) · Journal of Chemical & Engineering Data · doi:10.1021/acs.jced.5c00651

Vortex-assisted liquid-liquid microextraction based on natural deep eutectic solvents for the determination of pyrethroid pesticides in urine

Zhang, P., Feng, S., Feng, Y., Lu, J., Han, Z., Quinto, M., Sun, T., & Jing, X. (2026) · Journal of Chromatography B · doi:10.1016/j.jchromb.2026.125246

Synthesis and characterisation of Deep Eutectic Solvents for the extraction of selected pesticide residues in different spices and herbsPreprint

Dlamini, S. S., Makwakwa, T. A., Chokwe, R. C., & Kgomo, H. (2026) · SSRN Electronic Journal · doi:10.2139/ssrn.7460684

Thymol-based deep eutectic solvents: a comprehensive overview of classifications, preparation methods, stability, and thermophysical properties

Sadeghi, R., & Ebrahimi, N. (2026) · RSC Advances · doi:10.1039/d6ra05714d

Analytical strategies for pyrethroids' residues in environmental and food media: A critical review from traditional assays to advanced optical and electrochemical sensors and future perspectives

Liu, Y., Chen, C., Gao, M., Liu, T., Qin, H., & Wang, X. (2026) · Chemical Engineering Journal · doi:10.1016/j.cej.2026.183467

COSMO-RS-guided design of Type V deep eutectic solvents for vortex-assisted liquid-liquid microextraction of pesticides in fruit juices

Cai, Z., Li, X., Wang, J., Liu, F., Wang, Y., & Peng, Q. (2026) · Talanta · doi:10.1016/j.talanta.2026.130884

Cyclodextrin-assisted dispersive liquid-liquid microextraction based on solidification of floating organic droplets coupled with HPLC for the determination of pyrethroid residues in cereals

Jiang, H., Bi, X., Huang, X., Guo, X., Zou, Z., Li, Y., Jing, X., & Wu, J. (2022) · Acta Chromatographica · doi:10.1556/1326.2021.00991 · Cited by 5 · see citing works

Determination of Pyrethroid Pesticide Residues in Wheat Flour by HPLC

Xin-sheng, Z. (2013) · Guangzhou Chemical Industry

Multi-residue determination of organophosphorus pesticides and synthetic pyrethroids in wheat

Khan, I. A. T., Parveen, Z., Riazuddin, & Ahmed, M. F. (2007) · International Journal of Agriculture and Biology · Cited by 4 · see citing works

Solid‐phase extraction combined with dispersive liquid–liquid microextraction for the determination of pyrethroid pesticides in wheat and maize samples

Zhu, X., Jia, C., Zheng, Z., Feng, X., He, Y., & Zhao, E. (2016) · Journal of Separation Science · doi:10.1002/jssc.201600840 · Cited by 21 · see citing works

Simultaneous analysis of multiple pyrethroid pesticide residues in grains by HPLC-DAD

Cai-xi, H. (2015) · Cereals & Oils