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Observation of molecular layering in a confined water film and study of the layers viscoelastic properties

Antognozzi, M., Humphris, A. D. L., Miles, M. J.·2001·Applied Physics Letters

Abstract

A transverse dynamic force microscope, more commonly known as shear force microscope, has been used to investigate confined water films under shear. A cylindrically tapered glass probe was mounted perpendicularly to the sample surface. Pure water was confined between the probe and a freshly cleaved mica surface and a sinusoidal shear strain was applied by setting the probe into transverse oscillation. Repeated measurements of the probe oscillation amplitude and relative phase lag, at different tip-sample separations, exhibited a clear step-like behavior. The periodicity, recorded over several curves, ranged between 2.4 and 2.9 Å, which is similar to the diameter of the water molecule. The in-phase (elastic) and the out-of-phase (viscous) stress response of the confined water film was evaluated (from the experimental data) by assuming a linear viscoelastic behavior. Finally, by modeling the water film with the Maxwell mechanical model, the values for the shear viscosity and shear rigidity were obtained.

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Metadata

Authors
Antognozzi, M., Humphris, A. D. L., & Miles, M. J.
Venue
Applied Physics Letters
Published
2001-01-15
Volume
78
Issue
3
Pages
300-302
ISSN
  • 0003-6951 (ISSN-L)
  • 1077-3118
OpenAlex
W2053578140
Cited by
198
References
2
FWCI
2.83
Type
journal article
Language
en
Open access
closed

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Antognozzi, M., Humphris, A. D. L., & Miles, M. J. (2001). Observation of molecular layering in a confined water film and study of the layers viscoelastic properties. Applied Physics Letters. https://doi.org/10.1063/1.1339997

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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