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Observation of molecular layering in a confined water film and study of the layers viscoelastic properties
Abstract
A transverse dynamic force microscope, more commonly known as shear force microscope, has been used to investigate confined water films under shear. A cylindrically tapered glass probe was mounted perpendicularly to the sample surface. Pure water was confined between the probe and a freshly cleaved mica surface and a sinusoidal shear strain was applied by setting the probe into transverse oscillation. Repeated measurements of the probe oscillation amplitude and relative phase lag, at different tip-sample separations, exhibited a clear step-like behavior. The periodicity, recorded over several curves, ranged between 2.4 and 2.9 Å, which is similar to the diameter of the water molecule. The in-phase (elastic) and the out-of-phase (viscous) stress response of the confined water film was evaluated (from the experimental data) by assuming a linear viscoelastic behavior. Finally, by modeling the water film with the Maxwell mechanical model, the values for the shear viscosity and shear rigidity were obtained.
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Cited by
Molecular Structure of Water at Interfaces: Wetting at the Nanometer Scale
Verdaguer, A., Sacha, G. M., Bluhm, H., & Salmeron, M. (2006) · Chemical Reviews · doi:10.1021/cr040376l · Cited by 627
Structured and viscous water in subnanometer gaps
Li, T.-D., Gao, J., Szoszkiewicz, R., Landman, U., & Riedo, E. (2007) · Physical Review B · doi:10.1103/physrevb.75.115415 · Cited by 359
Nonlinear Viscoelastic Dynamics of Nanoconfined Wetting Liquids
Li, T.-D., & Riedo, E. (2008) · Physical Review Letters · doi:10.1103/physrevlett.100.106102 · Cited by 104
Dynamic properties of confined hydration layers
Perkin, S., Goldberg, R., Chai, L., Kampf, N., & Klein, J. (2009) · Faraday Discuss. · doi:10.1039/b805244a · Cited by 89
Nanorheology by atomic force microscopy
Li, T.-D., Chiu, H.-C., Ortiz-Young, D., & Riedo, E. (2014) · Review of Scientific Instruments · doi:10.1063/1.4903353 · Cited by 38
Metadata
- Authors
- Antognozzi, M., Humphris, A. D. L., & Miles, M. J.
- Venue
- Applied Physics Letters
- Publisher
- AIP Publishing
- Published
- 2001-01-15
- Volume
- 78
- Issue
- 3
- Pages
- 300-302
- ISSN
- 0003-6951 (ISSN-L)
- 1077-3118
- OpenAlex
- W2053578140
- Cited by
- 198
- References
- 2
- FWCI
- 2.83
- Type
- journal article
- Language
- en
- Open access
- closed
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