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Integration of self-assembled diblock copolymers for semiconductor capacitor fabrication
Abstract
We combine a self-organizing diblock copolymer system with semiconductor processing to produce silicon capacitors with increased charge storage capacity over planar structures. Our process uses a diblock copolymer thin film as a mask for dry etching to roughen a silicon surface on a 30 nm length scale, which is well below photolithographic resolution limits. Electron microscopy correlates measured capacitance values with silicon etch depth, and the data agree well with a geometric estimate. This block copolymer nanotemplating process is compatible with standard semiconductor processing techniques and is scalable to large wafer dimensions.
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Citations
Cited by
Directing the self-assembly of block copolymers
Darling, S. B. (2007) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2007.05.004 · Cited by 1,019
Block copolymer based nanostructures: Materials, processes, and applications to electronics
Kim, H.-C., Park, S.-M., & Hinsberg, W. D. (2010) · Chemical Reviews · doi:10.1021/cr900159v · Cited by 1,017
Directed Assembly of Block Copolymer Blends into Nonregular Device-Oriented Structures
Stoykovich, M. P., Müller, M., Kim, S. O., Solak, H. H., Edwards, E. W., de Pablo, J. J., & Nealey, P. F. (2005) · Science · doi:10.1126/science.1111041 · Cited by 962
Nanostructure fabrication using block copolymers
Hamley, I. W. (2003) · Nanotechnology · doi:10.1088/0957-4484/14/10/201 · Cited by 773
Evolution of Block Copolymer Lithography to Highly Ordered Square Arrays
Tang, C., Lennon, E. M., Fredrickson, G. H., Kramer, E. J., & Hawker, C. J. (2008) · Science · doi:10.1126/science.1162950 · Cited by 624
Metadata
- Authors
- Black, C. T., Guarini, K. W., Milkove, K. R., Baker, S. M., Russell, T. P., & Tuominen, M. T.
- Venue
- Applied Physics Letters
- Publisher
- AIP Publishing
- Published
- 2001-07-16
- Volume
- 79
- Issue
- 3
- Pages
- 409-411
- ISSN
- 0003-6951 (ISSN-L)
- 1077-3118
- OpenAlex
- W1998241405
- Cited by
- 351
- References
- 0
- FWCI
- 12.94
- Type
- journal article
- Language
- en
- Open access
- closed
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- Black, C. T., Guarini, K. W., Milkove, K. R., Baker, S. M., Russell, T. P., & Tuominen, M. T. (2001). Integration of self-assembled diblock copolymers for semiconductor capacitor fabrication. Applied Physics Letters. https://doi.org/10.1063/1.1383805
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.