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Low-Frequency Negative Resistance in Thin Anodic Oxide Films
Abstract
Negative resistance and large current densities have been observed in the direct-current—voltage characteristics of five metal-oxide-metal sandwiches prepared from evaporated metal films. The systems studied and their voltages for maximum current are: Al-SiO-Au, 3.1 V; Al-Al2O3-Au, 2.9 V; Ta-Ta2O5-Au, 2.2 V; Zr-ZrO2-Au, 2.1 V; and Ti-TiO2-Au, 1.7 V. For aluminum oxide, which has been most extensively studied, the voltage for maximum current is independent of film thickness for films between 150 and 1000 Å thick; the phenomenon is not field dependent. Peak-to-valley ratios of 30:1 and current densities of 10 A/cm2 are typical. Maximum current densities at peak voltage are 25 A/cm2; minimum current densities are 0.01 A/cm2. Switching time from peak current to valley current is <0.5 μsec but negative resistance is not found for 60-cycle voltages. Establishment of the dc characteristics and dependence on temperature and atmosphere are described. Electron emission from aluminum oxide sandwiches can occur at 2.5 V. Space-charge-limited currents in the insulator provide a possible mechanism for the current-voltage curves and large currents below the voltage for maximum current through the oxide films. The mechanism responsible for negative resistance is uncertain.
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Metadata
- Authors
- Hickmott, T. W.
- Venue
- Journal of Applied Physics
- Publisher
- AIP Publishing
- Published
- 1962-09-01
- Volume
- 33
- Issue
- 9
- Pages
- 2669-2682
- ISSN
- 0021-8979 (ISSN-L)
- 1089-7550
- OpenAlex
- W2016562169
- Cited by
- 766
- References
- 0
- FWCI
- 25.44
- Type
- journal article
- Language
- en
- Open access
- closed
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