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Hardening-softening transition in Fe-doped Pb(Zr,Ti)O3 ceramics and evolution of the third harmonic of the polarization response
Open accessAbstract
It is shown that the phase angle of the third harmonic of polarization response (δ3) is very sensitive to the aging state of hard, Fe-doped lead zirconate titanate [Pb(Zr,Ti)O3 or PZT] ceramics and may thus provide rich information on processes responsible for aging in hard ferroelectrics. When hard PZT ceramics experience hardening (aged state)-softening (deaged state) transition, δ3 changes by about 90° at subswitching fields and by about 180° at switching conditions. Evolution of δ3 with time, temperature and electric field amplitude during deaging suggests that at least two mechanisms of charge migration, one short-range and one long-range, may participate in the deaging process.
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Citations
Cited by
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BiFeO 3 Ceramics: Processing, Electrical, and Electromechanical Properties
Rojac, T., Bencan, A., Malic, B., Tutuncu, G., Jones, J. L., Daniels, J. E., & Damjanovic, D. (2014) · Journal of the American Ceramic Society · doi:10.1111/jace.12982 · Cited by 482
Self-citationMechanisms of aging and fatigue in ferroelectrics
Genenko, Y. A., Glaum, J., Hoffmann, M. J., & Albe, K. (2015) · Materials Science and Engineering: B · doi:10.1016/j.mseb.2014.10.003 · Cited by 400
Complex Internal Bias Fields in Ferroelectric Hafnium Oxide
Schenk, T., Hoffmann, M., Ocker, J., Pešić, M., Mikolajick, T., & Schroeder, U. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b05773 · Cited by 280
Electric field cycling behavior of ferroelectric hafnium oxide
Schenk, T., Schroeder, U., Pešić, M., Popovici, M., Pershin, Y. V., & Mikolajick, T. (2014) · ACS Applied Materials & Interfaces · doi:10.1021/am504837r · Cited by 197
Metadata
- Authors
- Morozov, M. I., & Damjanovic, D.
- Venue
- Journal of Applied Physics
- Publisher
- AIP Publishing
- Published
- 2008-08-01
- Volume
- 104
- Issue
- 3
- ISSN
- 0021-8979 (ISSN-L)
- 1089-7550
- OpenAlex
- W1971222642
- Cited by
- 164
- References
- 0
- FWCI
- 3.37
- Type
- journal article
- Language
- en
- Open access
- green
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- CoChat. (2026). Citation check: Hardening-softening transition in Fe-doped Pb(Zr,Ti)O3 ceramics and evolution of the third harmonic of the polarization response. https://app.cochat.ai/papers/10.1063/1.2963704
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- Morozov, M. I., & Damjanovic, D. (2008). Hardening-softening transition in Fe-doped Pb(Zr,Ti)O3 ceramics and evolution of the third harmonic of the polarization response. Journal of Applied Physics. https://doi.org/10.1063/1.2963704
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