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Fracture of electrodes in lithium-ion batteries caused by fast charging
Open accessAbstract
During charging or discharging of a lithium-ion battery, lithium is extracted from one electrode and inserted into the other. This extraction-insertion reaction causes the electrodes to deform. An electrode is often composed of small active particles in a matrix. If the battery is charged at a rate faster than lithium can homogenize in an active particle by diffusion, the inhomogeneous distribution of lithium results in stresses that may cause the particle to fracture. The distributions of lithium and stress in a LiCoO2 particle are calculated. The energy release rates are then calculated for the particle containing preexisting cracks. These calculations predict the critical rate of charging and size of the particle, below which fracture is averted.
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Citations
Cites
Stress generation and fracture in lithium insertion materials
Christensen, J., & Newman, J. (2006) · Journal of Solid State Electrochemistry · doi:10.1007/s10008-006-0095-1 · Cited by 727
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Li, J., Adewuyi, K., Lotfi, N., Landers, R. G., & Park, J. (2018) · Applied Energy · doi:10.1016/j.apenergy.2018.01.011 · Cited by 623
A review of safety-focused mechanical modeling of commercial lithium-ion batteries
Zhu, J., Wierzbicki, T., & Li, W. (2018) · Journal of Power Sources · doi:10.1016/j.jpowsour.2017.12.034 · Cited by 482
Fracture of crystalline silicon nanopillars during electrochemical lithium insertion
Lee, S. W., McDowell, M. T., Berla, L. A., Nix, W. D., & Cui, Y. (2012) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1201088109 · Cited by 432
Micro‐ and Nano‐Structured Vanadium Pentoxide (V2O5) for Electrodes of Lithium‐Ion Batteries
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Metadata
- Authors
- Zhao, K., Pharr, M., Vlassak, J. J., & Suo, Z.
- Venue
- Journal of Applied Physics
- Publisher
- AIP Publishing
- Published
- 2010-10-01
- Volume
- 108
- Issue
- 7
- ISSN
- 0021-8979 (ISSN-L)
- 1089-7550
- OpenAlex
- W2158241985
- Cited by
- 428
- References
- 1
- FWCI
- 50.09
- Type
- journal article
- Language
- en
- Open access
- green
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- Zhao, K., Pharr, M., Vlassak, J. J., & Suo, Z. (2010). Fracture of electrodes in lithium-ion batteries caused by fast charging. Journal of Applied Physics. https://doi.org/10.1063/1.3492617
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.