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Microstructure basis for strong piezoelectricity in Pb-free Ba(Zr0.2Ti0.8)O3-(Ba0.7Ca0.3)TiO3 ceramics

Gao, Jinghui, Xue, Dezhen, Wang, Yu, Wang, Dong, Zhang, Lixue, Wu, Haijun, Guo, Shengwu, Bao, Huixin, Zhou, Chao, Liu, Wenfeng, Hou, Sen, Xiao, Ge, Ren, Xiaobing·2011·Applied Physics Letters

Abstract

In this letter, we use transmission electron microscopy to study the microstructure feature of recently reported Pb-free piezoceramic Ba(Zr0.2Ti0.8)O3-x(Ba0.7Ca0.3)TiO3 across its piezoelectricity-optimal morphotropic phase boundary (MPB) by varying composition and temperature, respectively. The domain structure evolutions during such processes show that in MPB regime, the domains become miniaturized down to nanometer size with a domain hierarchy, which coincides with the d33-maximum region. Further convergent beam electron diffraction measurement shows that rhombohedral and tetragonal crystal symmetries coexist among the miniaturized domains. Strong piezoelectricity reported in such a system is due to easy polarization rotation between the coexisting nano-scale tetragonal and rhombohedral domains.

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Metadata

Authors
Gao, J., Xue, D., Wang, Y., Wang, D., Zhang, L., Wu, H., Guo, S., Bao, H., Zhou, C., Liu, W., Hou, S., Xiao, G., & Ren, X.
Venue
Applied Physics Letters
Published
2011-08-29
Volume
99
Issue
9
ISSN
  • 0003-6951 (ISSN-L)
  • 1077-3118
OpenAlex
W2022768454
Cited by
271
References
20
FWCI
9.14
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Microstructure basis for strong piezoelectricity in Pb-free Ba(Zr0.2Ti0.8)O3-(Ba0.7Ca0.3)TiO3 ceramics. https://app.cochat.ai/papers/10.1063/1.3629784
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Gao, J., Xue, D., Wang, Y., Wang, D., Zhang, L., Wu, H., Guo, S., Bao, H., Zhou, C., Liu, W., Hou, S., Xiao, G., & Ren, X. (2011). Microstructure basis for strong piezoelectricity in Pb-free Ba(Zr0.2Ti0.8)O3-(Ba0.7Ca0.3)TiO3 ceramics. Applied Physics Letters. https://doi.org/10.1063/1.3629784

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