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Cited by 495

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Transient nucleation in condensed systems

Kelton, K. F., Greer, A. L., Thompson, C. V.·1983·The Journal of Chemical Physics

Abstract

Using classical nucleation theory we consider transient nucleation occurring in a one-component, condensed system under isothermal conditions. We obtain an exact closed-form expression for the time dependent cluster populations. In addition, a more versatile approach is developed: a numerical simulation technique which models directly the reactions by which clusters are produced. This simulation demonstrates the evolution of cluster populations and nucleation rate in the transient regime. Results from the simulation are verified by comparison with exact analytical solutions for the steady state. Experimental methods for measuring transient nucleation are assessed, and it is demonstrated that the observed behavior depends on the method used. The effect of preexisting cluster distributions is studied. Previous analytical and numerical treatments of transient nucleation are compared to the solutions obtained from the simulation. The simple expressions of Kashchiev are shown to give good descriptions of the nucleation behavior.

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Metadata

Authors
Kelton, K. F., Greer, A. L., & Thompson, C. V.
Venue
The Journal of Chemical Physics
Published
1983-12-15
Volume
79
Issue
12
Pages
6261-6276
ISSN
  • 0021-9606 (ISSN-L)
  • 1089-7690
OpenAlex
W2001373029
Cited by
495
References
1
FWCI
7.75
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Transient nucleation in condensed systems. https://app.cochat.ai/papers/10.1063/1.445731
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Kelton, K. F., Greer, A. L., & Thompson, C. V. (1983). Transient nucleation in condensed systems. The Journal of Chemical Physics. https://doi.org/10.1063/1.445731

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