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Transient nucleation in condensed systems
Abstract
Using classical nucleation theory we consider transient nucleation occurring in a one-component, condensed system under isothermal conditions. We obtain an exact closed-form expression for the time dependent cluster populations. In addition, a more versatile approach is developed: a numerical simulation technique which models directly the reactions by which clusters are produced. This simulation demonstrates the evolution of cluster populations and nucleation rate in the transient regime. Results from the simulation are verified by comparison with exact analytical solutions for the steady state. Experimental methods for measuring transient nucleation are assessed, and it is demonstrated that the observed behavior depends on the method used. The effect of preexisting cluster distributions is studied. Previous analytical and numerical treatments of transient nucleation are compared to the solutions obtained from the simulation. The simple expressions of Kashchiev are shown to give good descriptions of the nucleation behavior.
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Citations
Cites
Kinetische Behandlung der Keimbildung in übersättigten Dämpfen
Becker, R., & Döring, W. (1935) · Annalen der Physik · doi:10.1002/andp.19354160806 · Cited by 3,155
Cited by
Homogeneous nucleation: theory and experiment
Oxtoby, D. W. (1992) · Journal of Physics: Condensed Matter · doi:10.1088/0953-8984/4/38/001 · Cited by 674
Mechanism of Formation of Monodispersed Colloids by Aggregation of Nanosize Precursors
Privman, V., Goia, D. V., Park, J., & Matijević, E. (1999) · Journal of Colloid and Interface Science · doi:10.1006/jcis.1999.6106 · Cited by 386
Crystal grain nucleation in amorphous silicon
Spinella, C., Lombardo, S., & Priolo, F. (1998) · Journal of Applied Physics · doi:10.1063/1.368873 · Cited by 356
Metadata
- Authors
- Kelton, K. F., Greer, A. L., & Thompson, C. V.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1983-12-15
- Volume
- 79
- Issue
- 12
- Pages
- 6261-6276
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2001373029
- Cited by
- 495
- References
- 1
- FWCI
- 7.75
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kelton, K. F., Greer, A. L., & Thompson, C. V. (1983). Transient nucleation in condensed systems. The Journal of Chemical Physics. https://doi.org/10.1063/1.445731
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