The DOI matches its Crossref record; 18 of the 18 references it cites were found in a registry or an index.
The melting behavior of organic materials confined in porous solids
Abstract
The solid–liquid phase transition temperatures and heats of fusion ΔHf of nonpolar organic solids confined in the pores of controlled pore glasses were measured by differential scanning calorimetry. The pore diameters d were in the range of 40–730 Å and the organics studied were cis-decalin, trans-decalin, cyclohexane, benzene, chlorobenzene, naphthalene, and heptane. In accordance with previous reports on studies of primarily inorganic materials, the melting point of the pore solid T(d) decreased with decreasing pore diameter. In addition, a large reduction in the bulk enthalpy of fusion ΔHf of the pore solid was measured, which apparently has not been studied in detail by other workers. A linear correlation was found between the melting point depression (ΔTm) and the reciprocal diameter, as predicted by theories of solidification in a capillary. The calculated values of the solid–liquid interfacial energy σsl were in reasonable agreement with values reported in the literature based on other methods of measurement.
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CRC Handbook of Chemistry and Physics
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Size effect on the melting temperature of gold particles
Buffat, P., & Borel, J.-P. (1976) · Physical Review A · doi:10.1103/physreva.13.2287 · Cited by 3,362
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A new method for the simultaneous determination of the size and shape of pores: the thermoporometry
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Thermodynamic theory of size dependence of melting temperature in metals
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Motions and Relaxations of Confined Liquids
Granick, S. (1991) · Science · doi:10.1126/science.253.5026.1374 · Cited by 992
Confinement effects on freezing and melting
Christenson, H. K. (2001) · Journal of Physics: Condensed Matter · doi:10.1088/0953-8984/13/11/201 · Cited by 567
Solid lipid nanoparticles for targeted brain drug delivery.
BLASI, P., GIOVAGNOLI, S., SCHOUBBEN, A., RICCI, M., & ROSSI, C. (2007) · Advanced Drug Delivery Reviews · doi:10.1016/j.addr.2007.04.011 · Cited by 506
Crystallization and orientation of isotactic poly(propylene) in cylindrical nanopores
Reid, D. K., Ehlinger, B. A., Shao, L., & Lutkenhaus, J. L. (2014) · Journal of Polymer Science Part B: Polymer Physics · doi:10.1002/polb.23577 · Cited by 17
Metadata
- Authors
- Jackson, C. L., & McKenna, G. B.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1990-12-15
- Volume
- 93
- Issue
- 12
- Pages
- 9002-9011
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2053334003
- Cited by
- 874
- References
- 18
- FWCI
- 5.54
- Type
- journal article
- Language
- en
- Open access
- closed
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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