The DOI matches its Crossref record; 39 of the 39 references it cites were found in a registry or an index.
The organometallic active site of [Fe]hydrogenase: Models and entatic states
Open accessAbstract
The simple organometallic, (μ-S 2 )Fe 2 (CO) 6 , serves as a precursor to synthetic analogues of the chemically rudimentary iron-only hydrogenase enzyme active site. The fundamental properties of the (μ-SCH 2 CH 2 CH 2 S)[Fe(CO) 3 ] 2 compound, including structural mobility and regioselectivity in cyanide/carbon monoxide substitution reactions, relate to the enzyme active site in the form of transition-state structures along reaction paths rather than ground-state structures. Even in the absence of protein-based active-site organization, the ground-state structural model complexes are shown to serve as hydrogenase enzyme reaction models, H 2 uptake and H 2 production, with the input of photo- or electrochemical energy, respectively.
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Cited by
Chatenet, M., Pollet, B. G., Dekel, D. R., Dionigi, F., Deseure, J., Millet, P., Braatz, R. D., Bazant, M. Z., Eikerling, M., Staffell, I., et al. (2022) · Chemical Society Reviews · doi:10.1039/d0cs01079k · Cited by 2,025
Earth-abundant hydrogen evolution electrocatalysts
McKone, J. R., Marinescu, S. C., Brunschwig, B. S., Winkler, J. R., & Gray, H. B. (2014) · Chem. Sci. · doi:10.1039/c3sc51711j · Cited by 727
Thoi, V. S., Sun, Y., Long, J. R., & Chang, C. J. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35272a · Cited by 668
Singh, W. M., Baine, T., Kudo, S., Tian, S., Ma, X. A. N., Zhou, H., DeYonker, N. J., Pham, T. C., Bollinger, J. C., Baker, D. L., et al. (2012) · Angewandte Chemie · doi:10.1002/ange.201200082 · Cited by 66
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Metadata
- Authors
- Darensbourg, M. Y., Lyon, E. J., Zhao, X., & Georgakaki, I. P.
- Venue
- Proceedings of the National Academy of Sciences
- Published
- 2003-03-17
- Volume
- 100
- Issue
- 7
- Pages
- 3683-3688
- ISSN
- 0027-8424 (ISSN-L)
- 1091-6490
- OpenAlex
- W1969520480
- Cited by
- 275
- References
- 39
- FWCI
- 12.65
- Type
- journal article
- Language
- en
- Open access
- green
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- Darensbourg, M. Y., Lyon, E. J., Zhao, X., & Georgakaki, I. P. (2003). The organometallic active site of [Fe]hydrogenase: Models and entatic states. Proceedings of the National Academy of Sciences. https://doi.org/10.1073/pnas.0536955100
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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