The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Enhancing electrochemical intermediate solvation through electrolyte anion selection to increase nonaqueous Li–O 2 battery capacity
Open accessAbstract
Significance: The Li–air battery has attracted significant interest as a potential high-energy alternative to Li-ion batteries. However, the battery discharge product, lithium peroxide, is both electronically insulative and insoluble in nonaqueous electrolytes. It therefore passivates the battery cathode as it is uniformly deposited and disallows the battery to achieve even a modest fraction of its potential electrochemical capacity. Our objective is to circumvent this challenge by enhancing the solubility of electrochemically formed intermediate species. We present a rational basis for electrolyte (i.e., solvent and salt) selection for nonaqueous Li–air batteries and demonstrate a selection criterion for an electrolyte salt that increases the stability of Li + in solution, thereby triggering a solution-based process that allows significantly improved battery capacities.
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Cites
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
Beitrag zur Theorie des Ferromagnetismus
Ising, E. (1925) · Zeitschrift für Physik · doi:10.1007/bf02980577 · Cited by 3,871
Cited by
Review on High‐Loading and High‐Energy Lithium–Sulfur Batteries
Peng, H., Huang, J., Cheng, X., & Zhang, Q. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201700260 · Cited by 1,746
Advances in understanding mechanisms underpinning lithium–air batteries
Aurbach, D., McCloskey, B. D., Nazar, L. F., & Bruce, P. G. (2016) · Nature Energy · doi:10.1038/nenergy.2016.128 · Cited by 1,254
Self-citationRegulating the Inner Helmholtz Plane for Stable Solid Electrolyte Interphase on Lithium Metal Anodes
Yan, C., Li, H.-R., Chen, X., Zhang, X.-Q., Cheng, X.-B., Xu, R., Huang, J.-Q., & Zhang, Q. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b05029 · Cited by 769
Gao, X., Chen, Y., Johnson, L., & Bruce, P. G. (2016) · Nature Materials · doi:10.1038/nmat4629 · Cited by 599
Critical Challenges in Rechargeable Aprotic Li–O2 Batteries
Feng, N., He, P., & Zhou, H. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201502303 · Cited by 423
Metadata
- Authors
- Burke, C. M., Pande, V., Khetan, A., Viswanathan, V., & McCloskey, B. D.
- Venue
- Proceedings of the National Academy of Sciences
- Published
- 2015-07-13
- Volume
- 112
- Issue
- 30
- Pages
- 9293-9298
- ISSN
- 0027-8424 (ISSN-L)
- 1091-6490
- OpenAlex
- W1782726582
- Cited by
- 348
- References
- 2
- FWCI
- 21.17
- Type
- journal article
- Language
- en
- Open access
- green
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- Burke, C. M., Pande, V., Khetan, A., Viswanathan, V., & McCloskey, B. D. (2015). Enhancing electrochemical intermediate solvation through electrolyte anion selection to increase nonaqueous Li–O 2 battery capacity. Proceedings of the National Academy of Sciences. https://doi.org/10.1073/pnas.1505728112
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