The DOI matches its Crossref record; 43 of the 43 references it cites were found in a registry or an index.
Structural and thermodynamic limits of layer thickness in 2D halide perovskites
Open accessAbstract
Significance: Organic–inorganic hybrid perovskites are exciting new solar cell materials. In 2D perovskites, the 3D structure is spatially interrupted by a layer of intercalated ions, which may alter both stability and functionality. A major question concerns the limit to which the 2D architecture can be maintained as the thickness of the layers increases. A combination of synthetic chemistry, crystallography, and spectroscopy was used to obtain and identify the thickest 2D halide perovskite characterized to date, having seven layers. Experimentally measured enthalpies of formation as a function of layer thickness show systematic behavior and that higher homologues are energetically unstable, placing a limit on the number of layers possible in a single-phase 2D perovskite. Their application in photovoltaics is discussed.
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Self-citationHigh-efficiency two-dimensional Ruddlesden–Popper perovskite solar cells
Tsai, H., Nie, W., Blancon, J.-C., Stoumpos, C. C., Asadpour, R., Harutyunyan, B., Neukirch, A. J., Verduzco, R., Crochet, J. J., Tretiak, S., et al. (2016) · Nature · doi:10.1038/nature18306 · Cited by 3,384
Self-citationHigh-efficiency solution-processed perovskite solar cells with millimeter-scale grains
Nie, W., Tsai, H., Asadpour, R., Blancon, J.-C., Neukirch, A. J., Gupta, G., Crochet, J. J., Chhowalla, M., Tretiak, S., Alam, M. A., et al. (2015) · Science · doi:10.1126/science.aaa0472 · Cited by 3,295
Self-citationOrganic–Inorganic Perovskites: Structural Versatility for Functional Materials Design
Saparov, B., & Mitzi, D. B. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00715 · Cited by 2,907
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Perovskite energy funnels for efficient light-emitting diodes
Yuan, M., Quan, L. N., Comin, R., Walters, G., Sabatini, R., Voznyy, O., Hoogland, S., Zhao, Y., Beauregard, E. M., Kanjanaboos, P., et al. (2016) · Nature Nanotechnology · doi:10.1038/nnano.2016.110 · Cited by 2,325
2D Homologous Perovskites as Light-Absorbing Materials for Solar Cell Applications
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Self-citationRuddlesden–Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors
Stoumpos, C. C., Cao, D. H., Clark, D. J., Young, J., Rondinelli, J. M., Jang, J. I., Hupp, J. T., & Kanatzidis, M. G. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.6b00847 · Cited by 2,130
Self-citationOrganic-Inorganic Hybrid Materials as Semiconducting Channels in Thin-Film Field-Effect Transistors
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Cited by
Li, X., Hoffman, J. M., & Kanatzidis, M. G. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c01006 · Cited by 1,085
Self-citationAdvanced Organic–Inorganic Hybrid Materials for Optoelectronic Applications
Zhou, K., Qi, B., Liu, Z., Wang, X., Sun, Y., & Zhang, L. (2024) · Advanced Functional Materials · doi:10.1002/adfm.202411671 · Cited by 228
Elemental segregation and dimensional separation in halide perovskite light-emitting diodes
Yang, S. J., Lee, Y. H., Tateno, K., & Dou, L. (2024) · Progress in Quantum Electronics · doi:10.1016/j.pquantelec.2024.100537 · Cited by 10
Metadata
- Authors
- Soe, C. M. M., Nagabhushana, G. P., Shivaramaiah, R., Tsai, H., Nie, W., Blancon, J.-C., Melkonyan, F., Cao, D. H., Traoré, B., Pedesseau, L., Kepenekian, M., Katan, C., Even, J., Marks, T. J., Navrotsky, A., Mohite, A. D., Stoumpos, C. C., & Kanatzidis, M. G.
- Venue
- Proceedings of the National Academy of Sciences
- Published
- 2018-12-18
- Volume
- 116
- Issue
- 1
- Pages
- 58-66
- ISSN
- 0027-8424 (ISSN-L)
- 1091-6490
- OpenAlex
- W2904314782
- Cited by
- 363
- References
- 43
- FWCI
- 11.20
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Soe, C. M. M., Nagabhushana, G. P., Shivaramaiah, R., Tsai, H., Nie, W., Blancon, J.-C., Melkonyan, F., Cao, D. H., Traoré, B., Pedesseau, L., Kepenekian, M., Katan, C., Even, J., Marks, T. J., Navrotsky, A., Mohite, A. D., Stoumpos, C. C., & Kanatzidis, M. G. (2019). Structural and thermodynamic limits of layer thickness in 2D halide perovskites. Proceedings of the National Academy of Sciences. https://doi.org/10.1073/pnas.1811006115
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