The DOI matches its Crossref record; 47 of the 47 references it cites were found in a registry or an index.
Identification of Fenton-like active Cu sites by heteroatom modulation of electronic density
Open accessAbstract
Significance: The Fenton-like process based on peroxymonosulfate (PMS) has been widely investigated and recognized as a promising alternative in recent years for the degradation of persistent organic pollutants. However, the sluggish kinetics of PMS activation results in prohibitive costs and substantial chemical inputs, impeding its practical applications in water purification. This work demonstrates that tuning the electronic structure of single-atom sites at the atomic level is a powerful approach to achieve superior PMS activation kinetics. The Cu-based catalyst with the optimized electronic structure exhibits superior performance over most of the state-of-the-art heterogeneous Fenton-like catalysts, while homogeneous Cu(II) shows very poor activity. This work provides insights into the electronic structure regulation of metal centers and structure–activity relationship at the atomic level.
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Cites
Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles
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Persulfate-Based Advanced Oxidation: Critical Assessment of Opportunities and Roadblocks
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Radical Generation by the Interaction of Transition Metals with Common Oxidants
Anipsitakis, G. P., & Dionysiou, D. D. (2004) · Environmental Science & Technology · doi:10.1021/es035121o · Cited by 3,098
Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction
Yang, H. B., Hung, S.-F., Liu, S., Yuan, K., Miao, S., Zhang, L., Huang, X., Wang, H.-Y., Cai, W., Chen, R., et al. (2018) · Nature Energy · doi:10.1038/s41560-017-0078-8 · Cited by 2,239
Self-citationHu, P., & Long, M. (2016) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2015.07.024 · Cited by 2,184
Chemistry of persulfates in water and wastewater treatment: A review
Wacławek, S., Lutze, H. V., Grübel, K., Padil, V. V. T., Černík, M., & Dionysiou, D. D. (2017) · Chemical Engineering Journal · doi:10.1016/j.cej.2017.07.132 · Cited by 1,874
Activated persulfate for organic chemical degradation: A review
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Activation of Peroxymonosulfate by Benzoquinone: A Novel Nonradical Oxidation Process
Zhou, Y., Jiang, J., Gao, Y., Ma, J., Pang, S.-Y., Li, J., Lu, X.-T., & Yuan, L.-P. (2015) · Environmental Science & Technology · doi:10.1021/acs.est.5b03595 · Cited by 1,294
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A Forward Vision for Chemodynamic Therapy: Issues and Opportunities
Zhao, P., Li, H., & Bu, W. (2023) · Angewandte Chemie International Edition · doi:10.1002/anie.202210415 · Cited by 308
Metadata
- Authors
- Zhou, X., Ke, M.-K., Huang, G.-X., Chen, C., Chen, W., Liang, K., Qu, Y., Yang, J., Wang, Y., Li, F., Yu, H.-Q., & Wu, Y.
- Venue
- Proceedings of the National Academy of Sciences
- Published
- 2022-02-14
- Volume
- 119
- Issue
- 8
- ISSN
- 0027-8424 (ISSN-L)
- 1091-6490
- OpenAlex
- W4213094266
- Cited by
- 451
- References
- 47
- FWCI
- 27.74
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Zhou, X., Ke, M.-K., Huang, G.-X., Chen, C., Chen, W., Liang, K., Qu, Y., Yang, J., Wang, Y., Li, F., Yu, H.-Q., & Wu, Y. (2022). Identification of Fenton-like active Cu sites by heteroatom modulation of electronic density. Proceedings of the National Academy of Sciences. https://doi.org/10.1073/pnas.2119492119
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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