Metal Organic Framework (ZIF-8)@ Alginate Nanocomposite for Micro Solid-Phase Extraction for Cd(II), Ni(II) and Co(II) in Water and Food Samples
Abstract
A novel nanocomposite was synthesized and characterized using FE-SEM, XRD, and FTIR techniques. The material was applied in a microsolid-phase extraction method for the trace determination of Cd(II), Ni(II), and Co(II). Key analytical parameters such as pH, adsorbent amount, eluent type and concentration, and sample and eluent volumes were optimized. Metal quantification was performed using FAAS, achieving a preconcentration factor of 60. Limits of detection were 3.87, 7.47, and 12.15 µg/kg for Cd(II), Ni(II), and Co(II), respectively. Method validation was conducted with certified reference materials and successfully applied to food and water samples from Türkiye.
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- Authors
- Soylak, M., Alparslan, M., & Ozalp, O.
- Affiliations
- Turkish Academy of Sciences (TR)
- Erciyes University (TR)
- Department of Chemistry, Faculty of Sciences, Erciyes University
- Corresponding author
- Soylak, Mustafa
- ORCID
- Soylak, Mustafa
- Venue
- Analytical Letters
- Publisher
- Informa UK Limited
- Published
- 2025-07
- Volume
- 59
- Issue
- 6
- Pages
- 993-1011
- ISSN
- 0003-2719 (ISSN-L)
- 1532-236X
- OpenAlex
- W4411877794
- Cited by
- 3
- References
- 72
- Citations by year
- 2026: 3
- FWCI
- 1.13
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Analytical Letters (publishedVersion)
- Erciyes University - AVESIS (submittedVersion)
- Topics
- Physical Sciences › Chemistry › Analytical Chemistry › Analytical chemistry methods development
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Physical Sciences › Environmental Science › Water Science and Technology › Environmental and Analytical Chemistry Studies
- Keywords
- ZIF-8, metal-organic frameworks, micro-solid phase extraction, cadmium, nickel, cobalt, trace metal analysis, preconcentration, food samples, water samples, heavy metal adsorption
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