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Thermodynamic theory of the lead zirconate-titanate solid solution system, part III: Curie constant and sixth-order polarization interaction dielectric stiffness coefficients

Haun, M. J., Zhuang, Z. Q., Furman, E., Jang, S. J., Cross, L. E.·1989·Ferroelectrics

Abstract

Vaiues of the Curie constant (C) and sixth-order polarization interaction dielectric stiffness coefficients (α112 and α123) are needed for the development of a thermodynamic theory for the entire lead zirconate-titanate (PZT) solid solution system. Low-temperature dielectric data measured on pure homogeneous polycrystalline PZT samples were used to determine values of these coefficients at several compositions across the phase diagram. Equations were then fitted to these data to determine the compositional dependence of the coefficients. The Curie constant was found to form a peak in the middle of the phase diagram at the PZT 50/50 composition.

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Metadata

Authors
Haun, M. J., Zhuang, Z. Q., Furman, E., Jang, S. J., & Cross, L. E.
Venue
Ferroelectrics
Published
1989-11
Volume
99
Issue
1
Pages
45-54
ISSN
  • 0015-0193 (ISSN-L)
  • 1563-5112
OpenAlex
W2046584105
Cited by
289
References
0
FWCI
3.80
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Thermodynamic theory of the lead zirconate-titanate solid solution system, part III: Curie constant and sixth-order polarization interaction dielectric stiffness coefficients. https://app.cochat.ai/papers/10.1080/00150198908221438
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Haun, M. J., Zhuang, Z. Q., Furman, E., Jang, S. J., & Cross, L. E. (1989). Thermodynamic theory of the lead zirconate-titanate solid solution system, part III: Curie constant and sixth-order polarization interaction dielectric stiffness coefficients. Ferroelectrics. https://doi.org/10.1080/00150198908221438

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