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Kinetic concepts of thermally stimulated reactions in solids: A view from a historical perspective
Abstract
Historical analysis suggests that the basic kinetic concepts of reactions in solids were inherited from homogeneous kinetics. These concepts rest upon the assumption of a single-step reaction that disagrees with the multiple-step nature of solid-state processes. The inadequate concepts inspire such unjustified anticipations of kinetic analysis as evaluating constant activation energy and/or deriving a single-step reaction mechanism for the overall process. A more adequate concept is that of the effective activation energy, which may vary with temperature and extent of conversion. The adequacy of this concept is illustrated by literature data as well as by experimental data on the thermal dehydration of calcium oxalate monohydrate and thermal decomposition of calcium carbonate, ammonium nitrate and 1,3,5,7- tetranitro-1,3,5,7-tetrazocine.
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Cited by
Khawam, A., & Flanagan, D. R. (2006) · Journal of Pharmaceutical Sciences · doi:10.1002/jps.20559 · Cited by 320
Samuelsson, L. N., Babler, M. U., & Moriana, R. (2015) · Fuel · doi:10.1016/j.fuel.2015.08.019 · Cited by 29
Rejitha, K. S., & Mathew, S. (2010) · Journal of Thermal Analysis and Calorimetry · doi:10.1007/s10973-010-0823-8 · Cited by 16
KINETIC STUDY ON PYROLYSIS OF NSSC BLACK LIQUOR IN A NITROGEN ATMOSPHERE
Zhao, Y., Bie, R., Lu, J., & Xiu, T. (2010) · Chemical Engineering Communications · doi:10.1080/00986440903359418 · Cited by 15
Kinetic Study of NSSC Black Liquor Combustion Using Different Kinetic Models
Zhao, Y., Bie, R., Lu, J., & Xiu, T. (2010) · Energy Sources, Part A: Recovery, Utilization, and Environmental Effects · doi:10.1080/15567030802578815 · Cited by 7
Metadata
- Authors
- Vyazovkin, S.
- Venue
- International Reviews in Physical Chemistry
- Publisher
- Informa UK Limited
- Published
- 2000-01
- Volume
- 19
- Issue
- 1
- Pages
- 45-60
- ISSN
- 0144-235X (ISSN-L)
- 1366-591X
- OpenAlex
- W2000533763
- Cited by
- 393
- References
- 0
- FWCI
- 8.21
- Type
- journal article
- Language
- en
- Open access
- closed
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