Application of Magnetic Fe 3 O 4 Alnus glutinosa Sawdust Biochar/SiO 2 /CTAB as a New Sorbent for Magnetic Solid Phase Extraction of Heavy Metals from Fruit and Waters Samples

Duran, Celal; Ozdes, Duygu

doi:10.1080/03067319.2021.1931856

Cited by 17Analytical chemistry methods developmentAdsorption and biosorption for pollutant removalEnvironmental and Analytical Chemistry Studies

Application of Magnetic Fe 3 O 4 Alnus glutinosa Sawdust Biochar/SiO 2 /CTAB as a New Sorbent for Magnetic Solid Phase Extraction of Heavy Metals from Fruit and Waters Samples

Duran, Celal, Ozdes, Duygu·2023·International Journal of Environmental Analytical Chemistry

DOI 10.1080/03067319.2021.1931856

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Abstract

The coating of magnetic Fe3O4Alnus glutinosa sawdust biochar with SiO2 and further functionalising by cetyltrimethyl ammonium bromide (CTAB), a cationic surfactant, was described for the first time in the current paper. The magnetic Fe3O4Alnus glutinosa sawdust biochar/SiO2/CTAB(MAGBC/SiO2/CTAB) was implemented to separate and preconcentrate the Cu2+, Cd2+, and Pb2+ions efficiently in waters and a number of fruit samples by solid-phase extraction (SPE) method. Adsorbent characterisation was realised by fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). Fundamental factors affecting the extraction yield of the analyte ions including solution pH, adsorbent amount, sample volume and desorption contact time were fully researched and optimised as 8.0, 0.25 g, 500 mL and 60 min, respectively, and the eluent was specified as 5.0 mL of 0.1 M of HCl solution. The adsorption equilibrium eventuated after 15 min of contact time and it was noticed that the chemisorption mechanism was dominant upon the analyte ions adsorption. The limits of detection (LOD) were calculated as 0.24, 0.62 and 1.55 µg L−1 and the limits of quantitation (LOQ) were determined as 0.81, 2.08, and 5.17 µg L−1 for Cu2+, Cd2+, and Pb2+ ions, respectively. The relative recoveries (RR%) were in the ranges of 93.3–103.4%, 92.5–102.8%, and 91.8–101.9% for Cu2+, Cd2+, and Pb2+ ions, respectively, while the relative standard deviations (RSD%) were obtained lower than 4.0% (n = 10) by applying the method at optimised conditions. The maximum adsorption capacities of MAGBC/SiO2/CTAB were obtained as 123.7, 80.0 and 118.5 mg g−1for Cu2+, Cd2+, and Pb2+ions, respectively. Consequently, the developed new, simple, rapid, sensitive, and economical SPE method based on MAGBC/SiO2/CTAB was successfully implemented to waters and some of the fruit samples to determine the Cu2+, Cd2+, and Pb2+ions simultaneously.

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Authors: Duran, C., & Ozdes, D.
Affiliations: Karadeniz Technical University (TR)
Gumushane University
Corresponding author: Duran, Celal
ORCID: Duran, Celal
Venue: International Journal of Environmental Analytical Chemistry
Publisher: Informa UK Limited
Published: 2021-06-14
Volume: 103
Issue: 16
Pages: 4857-4875
ISSN: 0306-7319 (ISSN-L)
1029-0397
DOI: 10.1080/03067319.2021.1931856
OpenAlex: W3172832870
Cited by: 17
References: 45
Citations by year: 2026: 4 · 2025: 2 · 2024: 5 · 2023: 5 · 2021: 1
FWCI: 1.38
Type: journal article
Language: en
Open access: closed
Locations: International Journal of Environmental & Analytical Chemistry (publishedVersion)
Topics: Physical Sciences › Chemistry › Analytical Chemistry › Analytical chemistry methods development
Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
Physical Sciences › Environmental Science › Water Science and Technology › Environmental and Analytical Chemistry Studies
Keywords: magnetic biochar, magnetite, silica coating, cetyltrimethylammonium bromide, magnetic solid-phase extraction, heavy metal preconcentration, copper, cadmium, lead, fruit samples, water samples, chemisorption, adsorption isotherms, adsorption kinetics, adsorption thermodynamics

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Application of Magnetic Fe 3 O 4 Alnus glutinosa Sawdust Biochar/SiO 2 /CTAB as a New Sorbent for Magnetic Solid Phase Extraction of Heavy Metals from Fruit and Waters Samples

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