The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Extraction of Am(III) and Eu(III) from Nitrate Solution with Purified Cyanex 301
Abstract
The extraction of tracer amounts of Am(III) and Eu(III) from nitrate medium with purified Cyanex 301™ in kerosene was studied. The slopes of logD/pH dependencies for Am and Eu are close to 3 and the logD/extractant concentration dependencies for Am and Eu are close to 2, respectively. The calculated extraction constants are 10−7.85 for Am and 10−11.62 for Eu at 25°C. Both the extraction constants and the separation factor of Am/Eu decrease with increasing extraction temperature. The extraction enthalpies of Am and Eu are 18.10 kJmol−1 and 43.65 kJmol−1, respectively. This extraction system provides a high selectivity for Am(III) over Eu(III) (at 25°C, separation factor SF=5.9×l03) which arises from greater covalent bonding tendency between sulfur donor atom and Am(III) in comparison with Eu(III).
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Cites
Solvent extraction characteristics of thiosubstituted organophosphinic acid extractants
Sole, K. C., & Hiskey, J. B. (1992) · Hydrometallurgy · doi:10.1016/0304-386x(92)90093-f · Cited by 200
The selective recovery of zinc with new thiophosphinic acids
RICKELTON, W. A., & BOYLE, R. J. (1990) · Solvent Extraction and Ion Exchange · doi:10.1080/07366299008918030 · Cited by 118
Research works printed but not linked: 8
- C. Musikas , “ Actinide —Lanthanide Group Separation Using Sulfur and Nitrogen Donor Extractants” inActinide/Lanthanide Separations Proceedings of an International Symposium, Honolulu,Hawaii , 16-22 December , 1984 . World Scientific Publishing , Singapore p. 19 , 1985 .
- Smith B.F., 1989, Solvent. Extr. Ion. Exch., 7, 749, 10.1080/07360298908962335 · doi:10.1080/07360298908962335
- Ensor D.D., 1988, Solvent Extr. Ion Exch, 6, 439, 10.1080/07366298808917948 · doi:10.1080/07366298808917948
- Sole K.C., 1993, Solvent. Extr. Ion Exch, 11, 783, 10.1080/07366299308918186 · DOI · Paper page
- S. Facon , M. Avila Rodriguez , G. Cote and D. Bauer ,Proceeding InternationalSolvent Extraction Conference, ISEC'94, London . p 557 .
- Yongjun Zhu, 1995, Radiochimica Acta, 68, 95, 10.1524/ract.1995.68.2.95 · doi:10.1524/ract.1995.68.2.95
- G.M. Ritcey and A.W. Ashbrook ,Solvent Extraction: Principles and Applications to Process Metallurgy, Part 1 , Elsevier , Amsterdam , 1984 , p. 98 .
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Cited by
Panak, P. J., & Geist, A. (2013) · Chemical Reviews · doi:10.1021/cr3003399 · Cited by 558
Paiva, A. P., & Malik, P. (2004) · Journal of Radioanalytical and Nuclear Chemistry · doi:10.1023/b:jrnc.0000034890.23325.b5 · Cited by 290
Jensen, M. P., & Bond, A. H. (2002) · Radiochimica Acta · doi:10.1524/ract.2002.90.4_2002.205 · Cited by 102
Xun, F., Yahong, X., Shuyun, X., Shaona, Z., & Zhengshui, H. (2002) · Solvent Extraction and Ion Exchange · doi:10.1081/sei-120004808 · Cited by 33
Fleitlikh, I. Y., Pashkov, G. L., Grigorieva, N. A., Nikiforova, L. K., Pleshkov, M. A., & Shneerson, Y. M. (2011) · Solvent Extraction and Ion Exchange · doi:10.1080/07366299.2011.595627 · Cited by 27
Metadata
- Authors
- Zhu, Y., Chen, J., & Jiao, R.
- Venue
- Solvent Extraction and Ion Exchange
- Publisher
- Informa UK Limited
- Published
- 1996-01
- Volume
- 14
- Issue
- 1
- Pages
- 61-68
- ISSN
- 0736-6299 (ISSN-L)
- 1532-2262
- OpenAlex
- W2037094673
- Cited by
- 267
- References
- 2
- FWCI
- 3.69
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhu, Y., Chen, J., & Jiao, R. (1996). Extraction of Am(III) and Eu(III) from Nitrate Solution with Purified Cyanex 301. Solvent Extraction and Ion Exchange. https://doi.org/10.1080/07366299608918326
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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