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Cited by 420

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N,N,N′,N′‐Tetraoctyl Diglycolamide (TODGA): A Promising Extractant for Actinide‐Partitioning from High‐Level Waste (HLW)

Ansari, S. A., Pathak, P. N., Manchanda, V. K., Husain, M., Prasad, A. K., Parmar, V. S.·2005·Solvent Extraction and Ion Exchange

Abstract

N,N,N′,N′‐Tetraoctyl diglycolamide (TODGA) has been evaluated as an extractant for the partitioning of minor actinides from simulated high level nuclear waste solutions. Acid uptake studies suggested that TODGA is more basic (KH: 4.1) as compared to TRUEX and DIAMEX solvents viz. CMPO (KH: 2.0) and DMDBTDMA (KH: 0.32), respectively. TODGA molecules display a tendency toward aggregation in n‐dodecane at lower acidities. Effect of diluent on the distribution behavior of Am(III) was studied employing diluents of different dielectric constants. N,N‐dialkyl amides with different alkyl groups viz. dibutyl decanamide (DBDA), di(2‐ethylhexyl) acetamide (D2EHAA), di(2‐ethylhexyl) propionamide (D2EHPRA), di(2‐ethylhexyl) isobutyramide (D2EHIBA), dihexyl octanamide (DHOA) and dihexyl decanamide (DHDA) were evaluated as phase modifiers. Distribution behavior of various metal ions viz. Am(III), Pu(IV), U(VI), Eu(III), Fe(III), Sr(II) and Cs(I) was studied from pure nitric acid solution as well as from simulated high level waste solution.

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Metadata

Authors
Ansari, S. A., Pathak, P. N., Manchanda, V. K., Husain, M., Prasad, A. K., & Parmar, V. S.
Venue
Solvent Extraction and Ion Exchange
Published
2005-07
Volume
23
Issue
4
Pages
463-479
ISSN
  • 0736-6299 (ISSN-L)
  • 1532-2262
OpenAlex
W2118611913
Cited by
420
References
8
FWCI
5.33
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: N,N,N′,N′‐Tetraoctyl Diglycolamide (TODGA): A Promising Extractant for Actinide‐Partitioning from High‐Level Waste (HLW). https://app.cochat.ai/papers/10.1081/sei-200066296
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Ansari, S. A., Pathak, P. N., Manchanda, V. K., Husain, M., Prasad, A. K., & Parmar, V. S. (2005). N,N,N′,N′‐Tetraoctyl Diglycolamide (TODGA): A Promising Extractant for Actinide‐Partitioning from High‐Level Waste (HLW). Solvent Extraction and Ion Exchange. https://doi.org/10.1081/sei-200066296

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