Cited by 570Carbon Dioxide Capture TechnologiesMembrane Separation and Gas TransportZeolite Catalysis and Synthesis

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Purification of Hydrogen by Pressure Swing Adsorption

SIRCAR, S., GOLDEN, T. C.·2000·Separation Science and Technology

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Abstract

Pressure swing adsorption (PSA) processes are used for the production of high purity hydrogen from steam methane reforming off-gas (SMROG) and refinery off-gases (ROG). A variety of commercial PSA processes for the production of H2 with or without a by-product (CO2 from SMROG), as well as PSA processes for direct production of ammonia synthesis gas (from SMROG), are reviewed. The equilibrium ad(de)sorption characteristics of the components of SMROG and ROG feed gas on an activated carbon, a zeolite, and a silica gel are reported, and the criteria for adsorbent selection in these PSA processes are discussed. Recent ideas to increase the H2 recovery from these PSA processes by integrating them with selective surface flow membranes or other PSA units are reviewed.

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Authors: SIRCAR, S., & GOLDEN, T. C.
Affiliations: Air Products (United States) (US)
ORCID: SIRCAR, S.
Venue: Separation Science and Technology
Publisher: Informa UK Limited
Published: 2000-01-05
Volume: 35
Issue: 5
Pages: 667-687
ISSN: 0149-6395 (ISSN-L)
1520-5754
DOI: 10.1081/ss-100100183
OpenAlex: W1998474834
Cited by: 570
References: 16
Citations by year: 2026: 30 · 2025: 37 · 2024: 40 · 2023: 50 · 2022: 39 · 2021: 45 · 2020: 42 · 2019: 43 · 2018: 34 · 2017: 16 · 2016: 25 · 2015: 18 · 2014: 16 · 2013: 19 · 2012: 23
FWCI: 9.91
Type: journal article
Language: en
Open access: closed
Locations: Separation Science and Technology (publishedVersion)
Topics: Physical Sciences › Chemical Engineering › Filtration and Separation › Carbon Dioxide Capture Technologies
Physical Sciences › Chemical Engineering › Filtration and Separation › Membrane Separation and Gas Transport
Physical Sciences › Chemistry › Inorganic Chemistry › Zeolite Catalysis and Synthesis
Keywords: hydrogen purification, pressure swing adsorption, ammonia synthesis gas, adsorption equilibrium, activated carbon, zeolites, silica gel, adsorbent selection, hydrogen recovery, carbon dioxide removal

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Purification of Hydrogen by Pressure Swing Adsorption

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