Discrimination among Carbonate Minerals by Raman Spectroscopy Using the Laser Microprobe
Abstract
Raman spectroscopy has been used to distinguish the individual carbonate minerals belonging to the calcite, dolomite, and aragonite structural groups. With the use of the in situ laser microprobe technique, it is demonstrated that particle-size effects do not hinder the mineral identification and that high precision in line position is achieved. Spectra can be obtained from samples in any form and provide rapid, nondestructive analyses on a microscopic scale of the hard-to-discriminate carbonate minerals.
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Spectral databases of Raman spectra for carbonates are still limited, especially for their solid-solution systems.
“Despite these advantages, spectral databases of Raman spectra for carbonates are still limited especially for their solid-solution systems [2, 15, 21–30].”
From Micro-Raman spectroscopic analysis on natural carbonates: linear relations found via biaxial plotting of peak frequencies for cation substituted species (2022) · cites this paper as [21]
In single-cation carbonates, substitution of the cation from Ca2+ to Fe2+, Mg2+, or Mn2+ leads to about 30-60 cm−1 of blue shift for the T and L modes.
“In the case of single cation carbonates, the substitution of the cation from Ca2+ to Fe2+, Mg2+, or Mn2+ leads to about 30–60 cm−1 of blue shift for T and L modes [2, 21–23].”
From Micro-Raman spectroscopic analysis on natural carbonates: linear relations found via biaxial plotting of peak frequencies for cation substituted species (2022) · cites this paper as [21]
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- Authors
- Herman, R. G., Bogdan, C. E., Sommer, A. J., & Simpson, D. R.
- Affiliations
- Lehigh University (US)
- Center for Surface and Coatings Research, Sinclair Laboratory, #7 (R.G.H., C.E.B., A.J.S.), and Department of Geological Sciences (D.R.S.), Lehigh University, Bethlehem, Pennsylvania 18015
- Venue
- Applied Spectroscopy
- Publisher
- SAGE Publications
- Published
- 1987-03
- Volume
- 41
- Issue
- 3
- Pages
- 437-440
- ISSN
- 0003-7028 (ISSN-L)
- 1943-3530
- OpenAlex
- W2160335632
- Cited by
- 130
- References
- 13
- Citations by year
- 2026: 4 · 2025: 3 · 2024: 3 · 2023: 7 · 2022: 5 · 2021: 3 · 2020: 7 · 2019: 3 · 2018: 6 · 2017: 7 · 2016: 3 · 2015: 4 · 2014: 4 · 2013: 6 · 2012: 6
- FWCI
- 1.19
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Applied Spectroscopy (publishedVersion)
- Funders
- U.S. Department of Energy
- Lehigh University
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Mineralogy and Gemology Studies
- Life Sciences › Biochemistry, Genetics and Molecular Biology › Biophysics › Spectroscopy Techniques in Biomedical and Chemical Research
- Social Sciences › Arts and Humanities › Archeology › Cultural Heritage Materials Analysis
- Keywords
- carbonate minerals, mineral discrimination, calcite, dolomite, aragonite, Raman spectroscopy, laser microprobe, particle size effects, in situ analysis
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