Synthesis of polymer montmorillonite nanocomposites by in situ intercalative polymerization

Zeng, Q H; Wang, D Z; Yu, A B; Lu, G Q

doi:10.1088/0957-4484/13/5/301

Cited by 163Polymer Nanocomposites and PropertiesClay minerals and soil interactionsLayered Double Hydroxides Synthesis and Applications

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Synthesis of polymer montmorillonite nanocomposites by in situ intercalative polymerization

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Zeng, Q H, Wang, D Z, Yu, A B, Lu, G Q·2002·Nanotechnology

DOI 10.1088/0957-4484/13/5/301

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Abstract

Two polymer–montmorillonite (MMT) nanocomposites have been synthesized by in situ intercalative polymerization. The styrene monomer is intercalated into the interlayer space of organically modified MMT, a layered clay mineral. Upon the intercalation, the complex is subsequently polymerized in the confinement environment of the interlayer space with a free radical initiator, 2,2-azobis isobutyronitrile. The aniline monomer is also intercalated and then polymerized within the interlayer space of sodium-and copper-MMT initiated by ammonium peroxodisulphate and interlayer copper cations respectively. X-ray diffraction indicates that the MMT layers are completely dispersed in the polystyrene matrix and an exfoliated structure has been obtained. The resulting polyaniline–MMT nanocomposites show a highly ordered structure of a single polyaniline layer stacked with the MMT layers. Fourier transform infrared spectra further confirm the intercalation and formation of both polymer–MMT nanocomposites.

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Authors: Zeng, Q. H., Wang, D. Z., Yu, A. B., & Lu, G. Q.
Affiliations: UNSW Sydney (AU)
General Research Institute for Nonferrous Metals (China) (CN)
The University of Queensland (AU)
Corresponding author: Lu, G Q
ORCID: Zeng, Q H
Yu, A B
Lu, G Q
Venue: Nanotechnology
Publisher: IOP Publishing
Published: 2002-08-19
Volume: 13
Issue: 5
Pages: 549-553
ISSN: 0957-4484 (ISSN-L)
DOI: 10.1088/0957-4484/13/5/301
OpenAlex: W2003002244
Cited by: 163
References: 63
Citations by year: 2026: 2 · 2025: 1 · 2024: 4 · 2023: 4 · 2022: 7 · 2021: 10 · 2020: 4 · 2019: 6 · 2018: 6 · 2017: 6 · 2016: 10 · 2015: 3 · 2014: 7 · 2013: 12 · 2012: 11
FWCI: 5.95
Type: journal article
Language: en
Open access: bronze
doi.org
Locations: Nanotechnology (publishedVersion)
Topics: Physical Sciences › Materials Science › Polymers and Plastics › Polymer Nanocomposites and Properties
Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Clay minerals and soil interactions
Physical Sciences › Materials Science › Materials Chemistry › Layered Double Hydroxides Synthesis and Applications
Keywords: polymer-clay nanocomposites, montmorillonite, in situ intercalative polymerization, polystyrene, polyaniline, organoclay, intercalation, exfoliation, azobisisobutyronitrile, clay minerals

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Synthesis of polymer montmorillonite nanocomposites by in situ intercalative polymerization

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