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The oceanic chemistry of the rare-earth elements
Abstract
Because of the unique chemical characteristics of the rare-earth elements (rees), they provide information as oceanic tracers of element source and reactivity. The absolute and relative concentrations of the rees in ocean waters reflect their input from rivers, by aeolian transport and from hydrothermal vents; their interaction with the biogeochemical cycle involving removal from surface waters by adsorption and oxidation at particle surfaces (probably with organic coatings) and deeper regeneration; and the effects of advective transport. Within the ree group, Ce anomalies occur in response to oceanic redox conditions; Eu anomalies in response to aeolian and hydrothermal input; and Nd isotopic variations reflect element sources. Both ree concentration patterns and Nd isotopic variations allow the effects of the vertical particle flux and of lateral advection to be separated.
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Cites
Rare earth elements in the Pacific and Atlantic Oceans
De Baar, H. J. W., Bacon, M. P., Brewer, P. G., & Bruland, K. W. (1985) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(85)90089-4 · Cited by 758
Rare-earth elements in seawater near hydrothermal vents
Klinkhammer, G., Elderfield, H., & Hudson, A. (1983) · Nature · doi:10.1038/305185a0 · Cited by 309
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Characterisation of early Archaean chemical sediments by trace element signatures
Bolhar, R., Kamber, B. S., Moorbath, S., Fedo, C. M., & Whitehouse, M. J. (2004) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2004.02.016 · Cited by 763
Wignall, P. B., & Hallam, A. (1992) · Palaeogeography, Palaeoclimatology, Palaeoecology · doi:10.1016/0031-0182(92)90182-5 · Cited by 466
Neoproterozoic chemostratigraphy
Halverson, G. P., Wade, B. P., Hurtgen, M. T., & Barovich, K. M. (2010) · Precambrian Research · doi:10.1016/j.precamres.2010.04.007 · Cited by 400
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Redox cycling of rare earth elements in the suboxic zone of the Black Sea
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Self-citationThe chromium isotopic composition of seawater and marine carbonates
Bonnand, P., James, R. H., Parkinson, I. J., Connelly, D. P., & Fairchild, I. J. (2013) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2013.09.001 · Cited by 177
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A persistently low level of atmospheric oxygen in Earth’s middle age
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Carbonate ooids of the Mesoarchaean Pongola Supergroup, South Africa
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Metadata
- Authors
- Elderfield, H.
- Venue
- Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences
- Publisher
- The Royal Society
- Published
- 1988-05-25
- Volume
- 325
- Issue
- 1583
- Pages
- 105-126
- ISSN
- 0080-4614 (ISSN-L)
- 2054-0272
- OpenAlex
- W1996695872
- Cited by
- 677
- References
- 2
- FWCI
- 14.86
- Type
- journal article
- Language
- en
- Open access
- closed
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