Note on an Approximation Treatment for Many-Electron Systems

Møller, Chr., Plesset, M. S.·1934·Physical Review

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A perturbation theory is developed for treating a system of $n$ electrons in which the Hartree-Fock solution appears as the zero-order approximation. It is shown by this development that the first order correction for the energy and the charge density of the system is zero. The expression for the second-order correction for the energy greatly simplifies because of the special property of the zero-order solution. It is pointed out that the development of the higher approximation involves only calculations based on a definite one-body problem.

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Authors: Møller, C., & Plesset, M. S.
Venue: Physical Review
Publisher: American Physical Society (APS)
Published: 1934-10-01
Volume: 46
Issue: 7
Pages: 618-622
ISSN: 0031-899X (ISSN-L)
DOI: 10.1103/physrev.46.618
OpenAlex: W2044940178
Cited by: 14,614
References: 0
FWCI: 2.27
Type: journal article
Language: en
Open access: closed

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Note on an Approximation Treatment for Many-Electron Systems

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